Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)

Schiff base ligand N,N′-bis(o-vanillinidene) ethylenediamine (o-VEDH2) has been employed to synthesize new [CoIICoIV(o-VED)(OAc)2(μ2-OAc)(OMe)]•MeOH (1) and [Co2IV(o-VED)2(en)2(NCCH3)(OCH3)][La(NO3)6](NO3−)•2MeOH•MeCN•H2O (2) metal–organic frameworks (MOFs) that have interesting single molecule magn...

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Main Authors: Mithun Kumar Ghosh, Barun Jana, Tanmay Kumar Ghorai
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-11-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2020.571223/full
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author Mithun Kumar Ghosh
Barun Jana
Tanmay Kumar Ghorai
Tanmay Kumar Ghorai
author_facet Mithun Kumar Ghosh
Barun Jana
Tanmay Kumar Ghorai
Tanmay Kumar Ghorai
author_sort Mithun Kumar Ghosh
collection DOAJ
description Schiff base ligand N,N′-bis(o-vanillinidene) ethylenediamine (o-VEDH2) has been employed to synthesize new [CoIICoIV(o-VED)(OAc)2(μ2-OAc)(OMe)]•MeOH (1) and [Co2IV(o-VED)2(en)2(NCCH3)(OCH3)][La(NO3)6](NO3−)•2MeOH•MeCN•H2O (2) metal–organic frameworks (MOFs) that have interesting single molecule magnets (SMMs) property. The synthesized complexes are characterized by single crystal X-ray diffraction, fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy, and squid magnetic measurement. Single crystal X-ray data show that both complexes crystallize in the monoclinic crystal system with P21/c(14) and P21/n(14) space groups and generate unique MOF-like structures. Overall, both the metal centers of 1 form octahedral geometry with a butterfly core structure. Variable temperature (T) and field (H) solid-state direct-current (dc) and alternative current (ac) magnetic susceptibility measurements were performed on both the complexes over 1.8 to 300 K, which exhibited a ground state spins (S) of 4 and 5 of complexes 1 and 2, respectively. The AC out-phase and in-phase properties of complexes show SMMs. Other properties such as optical, sensing, and DNA-binding interactions were also investigated by the complexes. Complexes 1 and 2 have energy band gaps of 3.7 and 3.03 eV indicating semiconductor properties. Simultaneously, complex 1 was found to sense H2O2 with a rate constant (k) = 1.59 × 10−4 s−1, whereas complex 2 was found to bind with calf-thymus–DNA by intercalation mode with binding constant (Kb) of 1.22 × 105 M−1.
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spelling doaj.art-3bfb213bf0ff4191a0e92651ff6e914e2022-12-21T23:39:21ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462020-11-01810.3389/fchem.2020.571223571223Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)Mithun Kumar Ghosh0Barun Jana1Tanmay Kumar Ghorai2Tanmay Kumar Ghorai3Nanomaterials and Crystal Designing Laboratory, Department of Chemistry Indira Gandhi National Tribal University, Amarkantak, IndiaDepartment of Chemistry, Malaviya National Institute of Technology, Jaipur, IndiaNanomaterials and Crystal Designing Laboratory, Department of Chemistry Indira Gandhi National Tribal University, Amarkantak, IndiaNanomaterials and Crystal Designing Laboratory, Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur, IndiaSchiff base ligand N,N′-bis(o-vanillinidene) ethylenediamine (o-VEDH2) has been employed to synthesize new [CoIICoIV(o-VED)(OAc)2(μ2-OAc)(OMe)]•MeOH (1) and [Co2IV(o-VED)2(en)2(NCCH3)(OCH3)][La(NO3)6](NO3−)•2MeOH•MeCN•H2O (2) metal–organic frameworks (MOFs) that have interesting single molecule magnets (SMMs) property. The synthesized complexes are characterized by single crystal X-ray diffraction, fourier transform infrared spectroscopy (FTIR), UV-visible spectroscopy, and squid magnetic measurement. Single crystal X-ray data show that both complexes crystallize in the monoclinic crystal system with P21/c(14) and P21/n(14) space groups and generate unique MOF-like structures. Overall, both the metal centers of 1 form octahedral geometry with a butterfly core structure. Variable temperature (T) and field (H) solid-state direct-current (dc) and alternative current (ac) magnetic susceptibility measurements were performed on both the complexes over 1.8 to 300 K, which exhibited a ground state spins (S) of 4 and 5 of complexes 1 and 2, respectively. The AC out-phase and in-phase properties of complexes show SMMs. Other properties such as optical, sensing, and DNA-binding interactions were also investigated by the complexes. Complexes 1 and 2 have energy band gaps of 3.7 and 3.03 eV indicating semiconductor properties. Simultaneously, complex 1 was found to sense H2O2 with a rate constant (k) = 1.59 × 10−4 s−1, whereas complex 2 was found to bind with calf-thymus–DNA by intercalation mode with binding constant (Kb) of 1.22 × 105 M−1.https://www.frontiersin.org/articles/10.3389/fchem.2020.571223/fullsynthesisschiff baseMOFsSMMssensing and CT-DNA 3
spellingShingle Mithun Kumar Ghosh
Barun Jana
Tanmay Kumar Ghorai
Tanmay Kumar Ghorai
Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
Frontiers in Chemistry
synthesis
schiff base
MOFs
SMMs
sensing and CT-DNA 3
title Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
title_full Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
title_fullStr Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
title_full_unstemmed Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
title_short Single Molecule Magnets of Co2 and Co2La MOFs Synthesized by New Schiff Base Ligand N,N′-bis(o-Vanillinidene) Ethylenediamine (o-VEDH2)
title_sort single molecule magnets of co2 and co2la mofs synthesized by new schiff base ligand n n bis o vanillinidene ethylenediamine o vedh2
topic synthesis
schiff base
MOFs
SMMs
sensing and CT-DNA 3
url https://www.frontiersin.org/articles/10.3389/fchem.2020.571223/full
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