New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent
Deep eutectic solvents (DESs) are an emerging class of materials that show promise for applications as inexpensive “designer” solvents with tunable properties. A detailed review of the current literature reveals a lack of predictive understanding of the microscopic mechanisms that govern the structu...
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Format: | Article |
Language: | English |
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Elsevier
2023-11-01
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Series: | Journal of Materials Research and Technology |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785423024080 |
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author | Izabela Klapiszewska Piotr Latos Anna Parus Sebastian Balicki Piotr Lodowski Kazimiera A. Wilk Teofil Jesionowski Anna Chrobok Łukasz Klapiszewski Agnieszka Ślosarczyk |
author_facet | Izabela Klapiszewska Piotr Latos Anna Parus Sebastian Balicki Piotr Lodowski Kazimiera A. Wilk Teofil Jesionowski Anna Chrobok Łukasz Klapiszewski Agnieszka Ślosarczyk |
author_sort | Izabela Klapiszewska |
collection | DOAJ |
description | Deep eutectic solvents (DESs) are an emerging class of materials that show promise for applications as inexpensive “designer” solvents with tunable properties. A detailed review of the current literature reveals a lack of predictive understanding of the microscopic mechanisms that govern the structure−property relationships in this class of solvents. They can dissolve both organic and inorganic compounds, including salts and metal oxides. Zinc oxide is used as a substrate for the synthesis of various task-specific materials, and has excellent antibacterial properties. In this work, both DES and a DES + ZnO combination were used for the first time as admixtures for cement composites, and were shown to improve the final properties of the cement matrix. The materials obtained exhibit good antibacterial properties, even with small amounts of zinc oxide, improved mechanical properties, and good durability when subjected to freezing–thawing cycles. |
first_indexed | 2024-03-07T23:23:38Z |
format | Article |
id | doaj.art-3bfdf081bf0244d4b365c36376549001 |
institution | Directory Open Access Journal |
issn | 2238-7854 |
language | English |
last_indexed | 2024-03-07T23:23:38Z |
publishDate | 2023-11-01 |
publisher | Elsevier |
record_format | Article |
series | Journal of Materials Research and Technology |
spelling | doaj.art-3bfdf081bf0244d4b365c363765490012024-02-21T05:25:21ZengElsevierJournal of Materials Research and Technology2238-78542023-11-0127542563New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solventIzabela Klapiszewska0Piotr Latos1Anna Parus2Sebastian Balicki3Piotr Lodowski4Kazimiera A. Wilk5Teofil Jesionowski6Anna Chrobok7Łukasz Klapiszewski8Agnieszka Ślosarczyk9Institute of Building Engineering, Faculty of Civil and Transport Engineering, Poznan University of Technology, Piotrowo 3, Poznan PL-60965, PolandDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, Gliwice PL-44100, PolandInstitute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, Poznan PL-60965, PolandDepartment of Engineering and Technology of Chemical Processes, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 29, Wroclaw PL-50370, PolandInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, Katowice PL-40007, PolandDepartment of Engineering and Technology of Chemical Processes, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 29, Wroclaw PL-50370, PolandInstitute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, Poznan PL-60965, PolandDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, Gliwice PL-44100, PolandInstitute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, Berdychowo 4, Poznan PL-60965, Poland; Corresponding author.Institute of Building Engineering, Faculty of Civil and Transport Engineering, Poznan University of Technology, Piotrowo 3, Poznan PL-60965, Poland; Corresponding author.Deep eutectic solvents (DESs) are an emerging class of materials that show promise for applications as inexpensive “designer” solvents with tunable properties. A detailed review of the current literature reveals a lack of predictive understanding of the microscopic mechanisms that govern the structure−property relationships in this class of solvents. They can dissolve both organic and inorganic compounds, including salts and metal oxides. Zinc oxide is used as a substrate for the synthesis of various task-specific materials, and has excellent antibacterial properties. In this work, both DES and a DES + ZnO combination were used for the first time as admixtures for cement composites, and were shown to improve the final properties of the cement matrix. The materials obtained exhibit good antibacterial properties, even with small amounts of zinc oxide, improved mechanical properties, and good durability when subjected to freezing–thawing cycles.http://www.sciencedirect.com/science/article/pii/S2238785423024080Sustainable developmentCement compositesDeep eutectic solventsAntibacterial properties |
spellingShingle | Izabela Klapiszewska Piotr Latos Anna Parus Sebastian Balicki Piotr Lodowski Kazimiera A. Wilk Teofil Jesionowski Anna Chrobok Łukasz Klapiszewski Agnieszka Ślosarczyk New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent Journal of Materials Research and Technology Sustainable development Cement composites Deep eutectic solvents Antibacterial properties |
title | New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
title_full | New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
title_fullStr | New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
title_full_unstemmed | New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
title_short | New insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
title_sort | new insights into sustainable cementitious composites doped with a hybrid system based on zinc oxide and a designable deep eutectic solvent |
topic | Sustainable development Cement composites Deep eutectic solvents Antibacterial properties |
url | http://www.sciencedirect.com/science/article/pii/S2238785423024080 |
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