Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative
Two new Mn(III) mixed-ligand complexes with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L] were prepared. Their structure was established by using elemental analysis, FTIR and UV/VIS spectroscopic methods, as well as m...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Faculty of Technology, Novi Sad
2005-01-01
|
| Series: | Acta Periodica Technologica |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-7188/2005/1450-71880536091C.pdf |
| _version_ | 1818346190160265216 |
|---|---|
| author | Cakić Suzana M. Nikolić Goran S. Stamenković Jakov V. Konstantinović Sandra S. |
| author_facet | Cakić Suzana M. Nikolić Goran S. Stamenković Jakov V. Konstantinović Sandra S. |
| author_sort | Cakić Suzana M. |
| collection | DOAJ |
| description | Two new Mn(III) mixed-ligand complexes with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L] were prepared. Their structure was established by using elemental analysis, FTIR and UV/VIS spectroscopic methods, as well as magnetic measurement. Replacement of the acetylacetonate ligand by the corresponding acid ligand has been confirmed in Mn(III) acetylacetonate. Based on the obtained experimental data and literature indications, structural formulae to these compounds were assigned. |
| first_indexed | 2024-12-13T17:14:19Z |
| format | Article |
| id | doaj.art-3c0913c34d564306a1bb256603d982e3 |
| institution | Directory Open Access Journal |
| issn | 1450-7188 |
| language | English |
| last_indexed | 2024-12-13T17:14:19Z |
| publishDate | 2005-01-01 |
| publisher | Faculty of Technology, Novi Sad |
| record_format | Article |
| series | Acta Periodica Technologica |
| spelling | doaj.art-3c0913c34d564306a1bb256603d982e32022-12-21T23:37:28ZengFaculty of Technology, Novi SadActa Periodica Technologica1450-71882005-01-01200536919810.2298/APT0536091CPhysico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivativeCakić Suzana M.Nikolić Goran S.Stamenković Jakov V.Konstantinović Sandra S.Two new Mn(III) mixed-ligand complexes with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L] were prepared. Their structure was established by using elemental analysis, FTIR and UV/VIS spectroscopic methods, as well as magnetic measurement. Replacement of the acetylacetonate ligand by the corresponding acid ligand has been confirmed in Mn(III) acetylacetonate. Based on the obtained experimental data and literature indications, structural formulae to these compounds were assigned.http://www.doiserbia.nb.rs/img/doi/1450-7188/2005/1450-71880536091C.pdfMn(III) complexesmaleate and hydroxylaminmaleate ligandphysico-chemical characterization |
| spellingShingle | Cakić Suzana M. Nikolić Goran S. Stamenković Jakov V. Konstantinović Sandra S. Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative Acta Periodica Technologica Mn(III) complexes maleate and hydroxylaminmaleate ligand physico-chemical characterization |
| title | Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| title_full | Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| title_fullStr | Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| title_full_unstemmed | Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| title_short | Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| title_sort | physico chemical characterization of mixed ligand complexes of mn iii based on the acetylacetonate and maleic acid and its hydroxylamine derivative |
| topic | Mn(III) complexes maleate and hydroxylaminmaleate ligand physico-chemical characterization |
| url | http://www.doiserbia.nb.rs/img/doi/1450-7188/2005/1450-71880536091C.pdf |
| work_keys_str_mv | AT cakicsuzanam physicochemicalcharacterizationofmixedligandcomplexesofmniiibasedontheacetylacetonateandmaleicacidanditshydroxylaminederivative AT nikolicgorans physicochemicalcharacterizationofmixedligandcomplexesofmniiibasedontheacetylacetonateandmaleicacidanditshydroxylaminederivative AT stamenkovicjakovv physicochemicalcharacterizationofmixedligandcomplexesofmniiibasedontheacetylacetonateandmaleicacidanditshydroxylaminederivative AT konstantinovicsandras physicochemicalcharacterizationofmixedligandcomplexesofmniiibasedontheacetylacetonateandmaleicacidanditshydroxylaminederivative |