Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand

Forty-eight suspended particulate matter (SPM) samples were collected from the Mun River, northeast Thailand and its junction with the Mekong River, to investigate the relationship between the distribution of rare earth elements (REE) in SPM and the soils in the watershed. The total REE contents (∑R...

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Main Authors: Kunhua Yang, Guilin Han, Jie Zeng, Wenxiang Zhou
Format: Article
Language:English
Published: PeerJ Inc. 2021-02-01
Series:PeerJ
Subjects:
Online Access:https://peerj.com/articles/10853.pdf
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author Kunhua Yang
Guilin Han
Jie Zeng
Wenxiang Zhou
author_facet Kunhua Yang
Guilin Han
Jie Zeng
Wenxiang Zhou
author_sort Kunhua Yang
collection DOAJ
description Forty-eight suspended particulate matter (SPM) samples were collected from the Mun River, northeast Thailand and its junction with the Mekong River, to investigate the relationship between the distribution of rare earth elements (REE) in SPM and the soils in the watershed. The total REE contents (∑REE) in SPM in the Mun River ranged from 78.5 to 377.8 mg/kg with the average of 189.3 mg/kg, which was lower than ∑REE of 222.3 mg/kg at the Mekong River (one sample at junction). The Post Archean Australia Shale (PAAS)-normalized ratios of light REE (LREE), middle REE (MREE) and heavy REE (HREE) were averaged to 1.0, 1.3 and 1.0, which showed a clear enrichment in MREE. In short, along the Mun River, the REE contents in SPM were decreasing, and the PAAS-normalized patterns of REE showed gradually flat. The REE content in SPM and soils are highest in the upper catchment, indicating that soil/bedrock is the most important source of REE in SPM. Additionally, the positive Eu anomaly was enhanced by the higher Ca content in SPM (R = 0.45), which may be caused by more feldspars or carbonates with Ca and Eu substituting Ca. The results present the REE behaviors of SPM in the Mun River and relationship between REE in SPM and soil/bedrock, the findings may support the other studies in catchment weathering.
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spelling doaj.art-3c20a52aaee944eca5df8c8eb06cb3372023-12-03T10:28:11ZengPeerJ Inc.PeerJ2167-83592021-02-019e1085310.7717/peerj.10853Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast ThailandKunhua YangGuilin HanJie ZengWenxiang ZhouForty-eight suspended particulate matter (SPM) samples were collected from the Mun River, northeast Thailand and its junction with the Mekong River, to investigate the relationship between the distribution of rare earth elements (REE) in SPM and the soils in the watershed. The total REE contents (∑REE) in SPM in the Mun River ranged from 78.5 to 377.8 mg/kg with the average of 189.3 mg/kg, which was lower than ∑REE of 222.3 mg/kg at the Mekong River (one sample at junction). The Post Archean Australia Shale (PAAS)-normalized ratios of light REE (LREE), middle REE (MREE) and heavy REE (HREE) were averaged to 1.0, 1.3 and 1.0, which showed a clear enrichment in MREE. In short, along the Mun River, the REE contents in SPM were decreasing, and the PAAS-normalized patterns of REE showed gradually flat. The REE content in SPM and soils are highest in the upper catchment, indicating that soil/bedrock is the most important source of REE in SPM. Additionally, the positive Eu anomaly was enhanced by the higher Ca content in SPM (R = 0.45), which may be caused by more feldspars or carbonates with Ca and Eu substituting Ca. The results present the REE behaviors of SPM in the Mun River and relationship between REE in SPM and soil/bedrock, the findings may support the other studies in catchment weathering.https://peerj.com/articles/10853.pdfRare earth elementSuspended particulate matterAgricultural catchmentWater/particle interactionMun RiverThailand
spellingShingle Kunhua Yang
Guilin Han
Jie Zeng
Wenxiang Zhou
Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
PeerJ
Rare earth element
Suspended particulate matter
Agricultural catchment
Water/particle interaction
Mun River
Thailand
title Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
title_full Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
title_fullStr Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
title_full_unstemmed Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
title_short Distribution, fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment, northeast Thailand
title_sort distribution fractionation and sources of rare earth elements in suspended particulate matter in a tropical agricultural catchment northeast thailand
topic Rare earth element
Suspended particulate matter
Agricultural catchment
Water/particle interaction
Mun River
Thailand
url https://peerj.com/articles/10853.pdf
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