Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate

In the title compound, [Co(C10H12NO2)3]·H2O, the CoIII ion is coordinated by three O atoms and three N atoms from three bidentate 2-ethoxy-6-(methyliminomethyl)phenolate ligands in a slightly distorted octahedral environment. The water molecule connects two ligands by O—H....

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Main Authors: Yin Dan Huang, Shu-Hua Zhang, Jiang Ke Qin, Fu Li Chen
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810040043
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author Yin Dan Huang
Shu-Hua Zhang
Jiang Ke Qin
Fu Li Chen
author_facet Yin Dan Huang
Shu-Hua Zhang
Jiang Ke Qin
Fu Li Chen
author_sort Yin Dan Huang
collection DOAJ
description In the title compound, [Co(C10H12NO2)3]·H2O, the CoIII ion is coordinated by three O atoms and three N atoms from three bidentate 2-ethoxy-6-(methyliminomethyl)phenolate ligands in a slightly distorted octahedral environment. The water molecule connects two ligands by O—H...O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412 (15) and 0.588 (15).
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spelling doaj.art-3c35c4f8c724430f96b40388313ce73b2022-12-22T01:40:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1399m139910.1107/S1600536810040043Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrateYin Dan HuangShu-Hua ZhangJiang Ke QinFu Li ChenIn the title compound, [Co(C10H12NO2)3]·H2O, the CoIII ion is coordinated by three O atoms and three N atoms from three bidentate 2-ethoxy-6-(methyliminomethyl)phenolate ligands in a slightly distorted octahedral environment. The water molecule connects two ligands by O—H...O hydrogen bonds. One terminal methyl group is disordered over two positions, with site-occupancy factors of 0.412 (15) and 0.588 (15).http://scripts.iucr.org/cgi-bin/paper?S1600536810040043
spellingShingle Yin Dan Huang
Shu-Hua Zhang
Jiang Ke Qin
Fu Li Chen
Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
Acta Crystallographica Section E
title Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
title_full Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
title_fullStr Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
title_full_unstemmed Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
title_short Tris[2-ethoxy-6-(methyliminomethyl)phenolato-κ2N,O1]cobalt(III) monohydrate
title_sort tris 2 ethoxy 6 methyliminomethyl phenolato amp 954 2n o1 cobalt iii monohydrate
url http://scripts.iucr.org/cgi-bin/paper?S1600536810040043
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AT shuhuazhang tris2ethoxy6methyliminomethylphenolatoamp9542no1cobaltiiimonohydrate
AT jiangkeqin tris2ethoxy6methyliminomethylphenolatoamp9542no1cobaltiiimonohydrate
AT fulichen tris2ethoxy6methyliminomethylphenolatoamp9542no1cobaltiiimonohydrate