Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate
In the title complex, [Fe(C64H64N8O4)Cl]·0.5C6H5Cl·H2O, the equatorial iron–pyrrole N atom distance (Fe—Np) is 2.065 (2) Å and the axial Fe—Cl distance is 2.207 (2)&#819...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811009299 |
| _version_ | 1818791668788232192 |
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| author | Mondher Dhifet Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri |
| author_facet | Mondher Dhifet Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri |
| author_sort | Mondher Dhifet |
| collection | DOAJ |
| description | In the title complex, [Fe(C64H64N8O4)Cl]·0.5C6H5Cl·H2O, the equatorial iron–pyrrole N atom distance (Fe—Np) is 2.065 (2) Å and the axial Fe—Cl distance is 2.207 (2) Å. The iron cation is displaced by 0.420 (4) Å from the 24-atom mean plane of the porphyrin core. The asymmetric unit contains a quarter of an [FeIII(C64H64N8O4)Cl] complex molecule, with a fourfold rotation axis passing through the central metal cation and the Cl ligand, along with disordered molecules of chlorobenzene and water of solvation; the solvent molecules were excluded from the refinement. |
| first_indexed | 2024-12-18T15:15:01Z |
| format | Article |
| id | doaj.art-3c4727b0d6e8436ea0ae07cd95c732b6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:15:01Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3c4727b0d6e8436ea0ae07cd95c732b62022-12-21T21:03:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m460m46110.1107/S1600536811009299Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrateMondher DhifetMohamed Salah BelkhiriaJean-Claude DaranHabib NasriIn the title complex, [Fe(C64H64N8O4)Cl]·0.5C6H5Cl·H2O, the equatorial iron–pyrrole N atom distance (Fe—Np) is 2.065 (2) Å and the axial Fe—Cl distance is 2.207 (2) Å. The iron cation is displaced by 0.420 (4) Å from the 24-atom mean plane of the porphyrin core. The asymmetric unit contains a quarter of an [FeIII(C64H64N8O4)Cl] complex molecule, with a fourfold rotation axis passing through the central metal cation and the Cl ligand, along with disordered molecules of chlorobenzene and water of solvation; the solvent molecules were excluded from the refinement.http://scripts.iucr.org/cgi-bin/paper?S1600536811009299 |
| spellingShingle | Mondher Dhifet Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate Acta Crystallographica Section E |
| title | Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate |
| title_full | Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate |
| title_fullStr | Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate |
| title_full_unstemmed | Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate |
| title_short | Chlorido{5,10,15,20-tetrakis[2-(2,2-dimethylpropanamido)phenyl]porphyrinato-κ4N,N′,N′′,N′′′}iron(III) chlorobenzene hemisolvate monohydrate |
| title_sort | chlorido 5 10 15 20 tetrakis 2 2 2 dimethylpropanamido phenyl porphyrinato amp 954 4n n amp 8242 n amp 8242 amp 8242 n amp 8242 amp 8242 amp 8242 iron iii chlorobenzene hemisolvate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811009299 |
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