Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.
The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticle...
Main Authors: | , , , , , , |
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Format: | Article |
Language: | English |
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Public Library of Science (PLoS)
2014-01-01
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Series: | PLoS ONE |
Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/pmid/24489869/?tool=EBI |
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author | Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark |
author_facet | Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark |
author_sort | Helen L Parker |
collection | DOAJ |
description | The metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties. |
first_indexed | 2024-12-13T15:04:42Z |
format | Article |
id | doaj.art-3c6ed0b20fcc4805930343cb996bc0ce |
institution | Directory Open Access Journal |
issn | 1932-6203 |
language | English |
last_indexed | 2024-12-13T15:04:42Z |
publishDate | 2014-01-01 |
publisher | Public Library of Science (PLoS) |
record_format | Article |
series | PLoS ONE |
spelling | doaj.art-3c6ed0b20fcc4805930343cb996bc0ce2022-12-21T23:41:02ZengPublic Library of Science (PLoS)PLoS ONE1932-62032014-01-0191e8719210.1371/journal.pone.0087192Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions.Helen L ParkerElizabeth L RylottAndrew J HuntJennifer R DodsonAndrew F TaylorNeil C BruceJames H ClarkThe metal accumulating ability of plants has previously been used to capture metal contaminants from the environment; however, the full potential of this process is yet to be realized. Herein, the first use of living plants to recover palladium and produce catalytically active palladium nanoparticles is reported. This process eliminates the necessity for nanoparticle extraction from the plant and reduces the number of production steps compared to traditional catalyst palladium on carbon. These heterogeneous plant catalysts have demonstrated high catalytic activity in Suzuki coupling reactions between phenylboronic acid and a range of aryl halides containing iodo-, bromo- and chloro- moieties.https://www.ncbi.nlm.nih.gov/pmc/articles/pmid/24489869/?tool=EBI |
spellingShingle | Helen L Parker Elizabeth L Rylott Andrew J Hunt Jennifer R Dodson Andrew F Taylor Neil C Bruce James H Clark Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. PLoS ONE |
title | Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. |
title_full | Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. |
title_fullStr | Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. |
title_full_unstemmed | Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. |
title_short | Supported palladium nanoparticles synthesized by living plants as a catalyst for Suzuki-Miyaura reactions. |
title_sort | supported palladium nanoparticles synthesized by living plants as a catalyst for suzuki miyaura reactions |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/pmid/24489869/?tool=EBI |
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