Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation

Nitrate in snow is subject to post-depositional processing, which leads to a net loss and redistribution within the snowpack. The relative importance of post-depositional loss processes such as the volatilization of nitric acid (HNO3) and photolysis of nitrate has long been debated. Changes in nitra...

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Main Authors: Kazushi Noro, Norimichi Takenaka
Format: Article
Language:English
Published: Norwegian Polar Institute 2020-12-01
Series:Polar Research
Subjects:
Online Access:https://polarresearch.net/index.php/polar/article/view/5146/12384
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author Kazushi Noro
Norimichi Takenaka
author_facet Kazushi Noro
Norimichi Takenaka
author_sort Kazushi Noro
collection DOAJ
description Nitrate in snow is subject to post-depositional processing, which leads to a net loss and redistribution within the snowpack. The relative importance of post-depositional loss processes such as the volatilization of nitric acid (HNO3) and photolysis of nitrate has long been debated. Changes in nitrate and chloride concentrations in the snowpack were investigated at H128 (69°23.584’S, 41°33.712’E), an Antarctic coastal site approximately 100 km from Syowa Station in East Antarctica from December 2015 to February 2016. Results indicate that chloride migrated to deeper sites within the snowpack under the influence of water vapour movement. Moreover, 50% of the nitrate on surface snow was lost to photolysis, and approximately 20% of the nitrate was absent at a depth of 40 cm. To enhance our knowledge of the Antarctic geochemical cycle, this study is the first to suggest chloride ion movement in snowpacks or significant nitrate loss for any Antarctic coastal site.
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spelling doaj.art-3c861b2bc3f347f2a30cc1a6c22285322022-12-21T20:08:17ZengNorwegian Polar InstitutePolar Research1751-83692020-12-013901910.33265/polar.v39.51465146Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigationKazushi Noro0Norimichi Takenaka1Research Institute of Environment, Agriculture and Fisheries, Osaka Prefecture, Habikino, Osaka, JapanGraduate School of Humanities and Sustainable System Sciences, Osaka Prefecture University, Sakai, Osaka, JapanNitrate in snow is subject to post-depositional processing, which leads to a net loss and redistribution within the snowpack. The relative importance of post-depositional loss processes such as the volatilization of nitric acid (HNO3) and photolysis of nitrate has long been debated. Changes in nitrate and chloride concentrations in the snowpack were investigated at H128 (69°23.584’S, 41°33.712’E), an Antarctic coastal site approximately 100 km from Syowa Station in East Antarctica from December 2015 to February 2016. Results indicate that chloride migrated to deeper sites within the snowpack under the influence of water vapour movement. Moreover, 50% of the nitrate on surface snow was lost to photolysis, and approximately 20% of the nitrate was absent at a depth of 40 cm. To enhance our knowledge of the Antarctic geochemical cycle, this study is the first to suggest chloride ion movement in snowpacks or significant nitrate loss for any Antarctic coastal site.https://polarresearch.net/index.php/polar/article/view/5146/12384antarcticageochemical cyclenitrogen cyclenitrogen oxidesozone
spellingShingle Kazushi Noro
Norimichi Takenaka
Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
Polar Research
antarctica
geochemical cycle
nitrogen cycle
nitrogen oxides
ozone
title Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
title_full Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
title_fullStr Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
title_full_unstemmed Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
title_short Post-depositional loss of nitrate and chloride in Antarctic snow by photolysis and sublimation: a field investigation
title_sort post depositional loss of nitrate and chloride in antarctic snow by photolysis and sublimation a field investigation
topic antarctica
geochemical cycle
nitrogen cycle
nitrogen oxides
ozone
url https://polarresearch.net/index.php/polar/article/view/5146/12384
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AT norimichitakenaka postdepositionallossofnitrateandchlorideinantarcticsnowbyphotolysisandsublimationafieldinvestigation