Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature

Fundamental study on material properties of lignocellulose fiber is important to understand the performance of composite materials. In this study, we explored several material properties of untreated, commercial and wood ash alkali retted fiber obtained from relatively less studied and traditionally...

Full description

Bibliographic Details
Main Authors: Krishna Prasad Kandel, Girja Mani Aryal, Bhanu Bhakta Neupane
Format: Article
Language:English
Published: Elsevier 2023-01-01
Series:Results in Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S221171562300111X
_version_ 1797798998433595392
author Krishna Prasad Kandel
Girja Mani Aryal
Bhanu Bhakta Neupane
author_facet Krishna Prasad Kandel
Girja Mani Aryal
Bhanu Bhakta Neupane
author_sort Krishna Prasad Kandel
collection DOAJ
description Fundamental study on material properties of lignocellulose fiber is important to understand the performance of composite materials. In this study, we explored several material properties of untreated, commercial and wood ash alkali retted fiber obtained from relatively less studied and traditionally important wild plant species Sterculia villosa (local name Murgilo or Mudilo) and Bauhinia vahlii fibers (local name Bharlo). Water sorption kinetics in all fiber types was measured at ambient temperature. Fickian model then was used to fit experimental sorption kinetic data and information on diffusion coefficients at early and late stages of sorption, average diffusion coefficient, sorption coefficient, and water permeability were obtained. The average diffusion coefficient (D) for untreated, wood ash alkali and commercial alkali treated Sterculia was found to be 10.6 × 10-13 m2/sec, 3.08 × 10-12 m2/sec, and 2.35 × 10-12 m2/sec; respectively. The corresponding values for Bauhinia fiber were found to be 6.8 × 10-13 m2/sec, 3.80 × 10-12 m2/sec, and 3.46 × 10-12 m2/sec; respectively. The equilibrium water sorption in the alkali treated fiber was significantly reduced due to removal of cementing materials and also increase of crystallinity. Significant decrease in mechanical strength of fiber in sorbed state was found. These findings will be useful to understand stability of fiber and potential end products such as paper sheets and reinforced composite materials exposed under different moisture conditions.
first_indexed 2024-03-13T04:13:21Z
format Article
id doaj.art-3c9b4c0c5f6b4e65a0cb6a15e06feec3
institution Directory Open Access Journal
issn 2211-7156
language English
last_indexed 2024-03-13T04:13:21Z
publishDate 2023-01-01
publisher Elsevier
record_format Article
series Results in Chemistry
spelling doaj.art-3c9b4c0c5f6b4e65a0cb6a15e06feec32023-06-21T06:52:21ZengElsevierResults in Chemistry2211-71562023-01-015100872Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperatureKrishna Prasad Kandel0Girja Mani Aryal1Bhanu Bhakta Neupane2Central Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu, NepalCentral Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu, NepalCorresponding author.; Central Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu, NepalFundamental study on material properties of lignocellulose fiber is important to understand the performance of composite materials. In this study, we explored several material properties of untreated, commercial and wood ash alkali retted fiber obtained from relatively less studied and traditionally important wild plant species Sterculia villosa (local name Murgilo or Mudilo) and Bauhinia vahlii fibers (local name Bharlo). Water sorption kinetics in all fiber types was measured at ambient temperature. Fickian model then was used to fit experimental sorption kinetic data and information on diffusion coefficients at early and late stages of sorption, average diffusion coefficient, sorption coefficient, and water permeability were obtained. The average diffusion coefficient (D) for untreated, wood ash alkali and commercial alkali treated Sterculia was found to be 10.6 × 10-13 m2/sec, 3.08 × 10-12 m2/sec, and 2.35 × 10-12 m2/sec; respectively. The corresponding values for Bauhinia fiber were found to be 6.8 × 10-13 m2/sec, 3.80 × 10-12 m2/sec, and 3.46 × 10-12 m2/sec; respectively. The equilibrium water sorption in the alkali treated fiber was significantly reduced due to removal of cementing materials and also increase of crystallinity. Significant decrease in mechanical strength of fiber in sorbed state was found. These findings will be useful to understand stability of fiber and potential end products such as paper sheets and reinforced composite materials exposed under different moisture conditions.http://www.sciencedirect.com/science/article/pii/S221171562300111XMaterial propertiesLignocellulose biomassFickian diffusionDiffusion coefficientMechanical strength
spellingShingle Krishna Prasad Kandel
Girja Mani Aryal
Bhanu Bhakta Neupane
Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
Results in Chemistry
Material properties
Lignocellulose biomass
Fickian diffusion
Diffusion coefficient
Mechanical strength
title Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
title_full Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
title_fullStr Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
title_full_unstemmed Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
title_short Kinetics of water sorption in single Sterculia and Bauhinia fibers at ambient temperature
title_sort kinetics of water sorption in single sterculia and bauhinia fibers at ambient temperature
topic Material properties
Lignocellulose biomass
Fickian diffusion
Diffusion coefficient
Mechanical strength
url http://www.sciencedirect.com/science/article/pii/S221171562300111X
work_keys_str_mv AT krishnaprasadkandel kineticsofwatersorptioninsinglesterculiaandbauhiniafibersatambienttemperature
AT girjamaniaryal kineticsofwatersorptioninsinglesterculiaandbauhiniafibersatambienttemperature
AT bhanubhaktaneupane kineticsofwatersorptioninsinglesterculiaandbauhiniafibersatambienttemperature