The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n
The solid-state structures of two metal–pyridine–sulfate compounds, namely catena-poly[[tetrakis(pyridine-κN)iron(II)]-μ-sulfato-κ2O:O′], [Fe(SO4)(C5H5N)4]n, (1), and catena-poly[[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′-[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O,O′:O′′-[tris(pyridine-...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018007557 |
| _version_ | 1818085278603018240 |
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| author | Duyen N. K. Pham Mrittika Roy Ava Kreider-Mueller James A. Golen David R. Manke |
| author_facet | Duyen N. K. Pham Mrittika Roy Ava Kreider-Mueller James A. Golen David R. Manke |
| author_sort | Duyen N. K. Pham |
| collection | DOAJ |
| description | The solid-state structures of two metal–pyridine–sulfate compounds, namely catena-poly[[tetrakis(pyridine-κN)iron(II)]-μ-sulfato-κ2O:O′], [Fe(SO4)(C5H5N)4]n, (1), and catena-poly[[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′-[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O,O′:O′′-[tris(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′], [Co3(SO4)3(C5H5N)11]n, (2), are reported. The iron compound (1) displays a polymeric structure, with infinite chains of FeII atoms adopting octahedral N4O2 coordination environments that involve four pyridine ligands and two bridging sulfate ligands. The cobalt compound (2) displays a polymeric structure, with infinite chains of CoII atoms. Two of the three Co centers have an octahedral N4O2 coordination environment that involves four pyridine ligands and two bridging sulfate ligands. The third Co center has an octahedral N3O3 coordination environment that involves three pyridine ligands, and two bridging sulfate ligands with one sulfate chelating the cobalt atom. |
| first_indexed | 2024-12-10T20:07:15Z |
| format | Article |
| id | doaj.art-3c9d6fd3a255497ebc52e1153996f100 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-10T20:07:15Z |
| publishDate | 2018-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-3c9d6fd3a255497ebc52e1153996f1002022-12-22T01:35:22ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-06-0174685786110.1107/S2056989018007557sj5556The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]nDuyen N. K. Pham0Mrittika Roy1Ava Kreider-Mueller2James A. Golen3David R. Manke4Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USADepartment of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USADepartment of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USADepartment of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USADepartment of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USAThe solid-state structures of two metal–pyridine–sulfate compounds, namely catena-poly[[tetrakis(pyridine-κN)iron(II)]-μ-sulfato-κ2O:O′], [Fe(SO4)(C5H5N)4]n, (1), and catena-poly[[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′-[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O,O′:O′′-[tris(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′], [Co3(SO4)3(C5H5N)11]n, (2), are reported. The iron compound (1) displays a polymeric structure, with infinite chains of FeII atoms adopting octahedral N4O2 coordination environments that involve four pyridine ligands and two bridging sulfate ligands. The cobalt compound (2) displays a polymeric structure, with infinite chains of CoII atoms. Two of the three Co centers have an octahedral N4O2 coordination environment that involves four pyridine ligands and two bridging sulfate ligands. The third Co center has an octahedral N3O3 coordination environment that involves three pyridine ligands, and two bridging sulfate ligands with one sulfate chelating the cobalt atom.http://scripts.iucr.org/cgi-bin/paper?S2056989018007557crystal structurepyridinesulfatetransition metalscrystal field theorycoordination chemistry |
| spellingShingle | Duyen N. K. Pham Mrittika Roy Ava Kreider-Mueller James A. Golen David R. Manke The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n Acta Crystallographica Section E: Crystallographic Communications crystal structure pyridine sulfate transition metals crystal field theory coordination chemistry |
| title | The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n |
| title_full | The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n |
| title_fullStr | The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n |
| title_full_unstemmed | The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n |
| title_short | The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n |
| title_sort | crystal structures of iron and cobalt pyridine py sulfates fe so4 py 4 n and co3 so4 3 py 11 n |
| topic | crystal structure pyridine sulfate transition metals crystal field theory coordination chemistry |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018007557 |
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