1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene
The TeIV atom in the title compound, [Te(C4H9)(C8H10Br)Cl2] or C12H19BrCl2Te, is in a distorted ψ-trigonal–bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48&a...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811023142 |
| _version_ | 1798025825509965824 |
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| author | Julio Zukerman-Schpector Ignez Caracelli Rafael Carlos Guadagnin Hélio A. Stefani Edward R. T. Tiekink |
| author_facet | Julio Zukerman-Schpector Ignez Caracelli Rafael Carlos Guadagnin Hélio A. Stefani Edward R. T. Tiekink |
| author_sort | Julio Zukerman-Schpector |
| collection | DOAJ |
| description | The TeIV atom in the title compound, [Te(C4H9)(C8H10Br)Cl2] or C12H19BrCl2Te, is in a distorted ψ-trigonal–bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)°]. Close intramolecular [Te...Br = 3.3444 (18) Å] and intermolecular [Te...Cl = 3.675 (3) Å] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C—H...Cl. |
| first_indexed | 2024-04-11T18:25:09Z |
| format | Article |
| id | doaj.art-3cbb5a7dd1e049a7ae6f033c372d46a7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:25:09Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3cbb5a7dd1e049a7ae6f033c372d46a72022-12-22T04:09:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677o1751o175210.1107/S16005368110231421-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-eneJulio Zukerman-SchpectorIgnez CaracelliRafael Carlos GuadagninHélio A. StefaniEdward R. T. TiekinkThe TeIV atom in the title compound, [Te(C4H9)(C8H10Br)Cl2] or C12H19BrCl2Te, is in a distorted ψ-trigonal–bipyramidal geometry, with the lone pair of electrons projected to occupy a position in the equatorial plane, and with the Cl atoms being mutually trans [172.48 (4)°]. Close intramolecular [Te...Br = 3.3444 (18) Å] and intermolecular [Te...Cl = 3.675 (3) Å] interactions are observed. The latter lead to centrosymmetric dimers which assemble into layers in the bc plane. The primary connections between layers are of the type C—H...Cl.http://scripts.iucr.org/cgi-bin/paper?S1600536811023142 |
| spellingShingle | Julio Zukerman-Schpector Ignez Caracelli Rafael Carlos Guadagnin Hélio A. Stefani Edward R. T. Tiekink 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene Acta Crystallographica Section E |
| title | 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene |
| title_full | 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene |
| title_fullStr | 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene |
| title_full_unstemmed | 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene |
| title_short | 1-[(Z)-1-Bromo-2-(butyldichloro-λ4-tellanyl)ethenyl]cyclohex-1-ene |
| title_sort | 1 z 1 bromo 2 butyldichloro amp 955 4 tellanyl ethenyl cyclohex 1 ene |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811023142 |
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