State-resolved studies of CO2 sticking to CO2 ice
Internal vibrations may affect the adsorption, scattering, and reactions of molecules impinging onto a surface. The energy of the ν3 antisymmetric stretch vibration of CO2 slightly exceeds the desorption energy of CO2 bound to CO2 ice. We use supersonic molecular beam techniques and rovibrationally...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2023-08-01
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| Series: | Frontiers in Chemistry |
| Subjects: | |
| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2023.1250711/full |
| _version_ | 1797352895342968832 |
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| author | Charlotte Jansen Ludo B. F. Juurlink |
| author_facet | Charlotte Jansen Ludo B. F. Juurlink |
| author_sort | Charlotte Jansen |
| collection | DOAJ |
| description | Internal vibrations may affect the adsorption, scattering, and reactions of molecules impinging onto a surface. The energy of the ν3 antisymmetric stretch vibration of CO2 slightly exceeds the desorption energy of CO2 bound to CO2 ice. We use supersonic molecular beam techniques and rovibrationally state-resolved excitation to determine whether this vibration affects condensation of gas phase CO2 to its ice. We detect sticking and CO2 ice formation using RAIRS and quantify the sticking probability using the King and Wells method with modulation of the vibrational excitation and Fourier transform based detection. We find that the influence of this vibration on the structure of the formed ice and on the sticking probability is negligible under our conditions. Based on our detection limit, we quantify the weighted average sticking probability at approximately 0.9 and the difference between the state-resolved and weighted average sticking probability as below 0.5%. |
| first_indexed | 2024-03-08T13:22:25Z |
| format | Article |
| id | doaj.art-3ccf205189a4430e8db93e840f41f0c4 |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-03-08T13:22:25Z |
| publishDate | 2023-08-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-3ccf205189a4430e8db93e840f41f0c42024-01-17T16:00:43ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462023-08-011110.3389/fchem.2023.12507111250711State-resolved studies of CO2 sticking to CO2 iceCharlotte JansenLudo B. F. JuurlinkInternal vibrations may affect the adsorption, scattering, and reactions of molecules impinging onto a surface. The energy of the ν3 antisymmetric stretch vibration of CO2 slightly exceeds the desorption energy of CO2 bound to CO2 ice. We use supersonic molecular beam techniques and rovibrationally state-resolved excitation to determine whether this vibration affects condensation of gas phase CO2 to its ice. We detect sticking and CO2 ice formation using RAIRS and quantify the sticking probability using the King and Wells method with modulation of the vibrational excitation and Fourier transform based detection. We find that the influence of this vibration on the structure of the formed ice and on the sticking probability is negligible under our conditions. Based on our detection limit, we quantify the weighted average sticking probability at approximately 0.9 and the difference between the state-resolved and weighted average sticking probability as below 0.5%.https://www.frontiersin.org/articles/10.3389/fchem.2023.1250711/fullCO2nu3state resolvedmolecular beamcondensation |
| spellingShingle | Charlotte Jansen Ludo B. F. Juurlink State-resolved studies of CO2 sticking to CO2 ice Frontiers in Chemistry CO2 nu3 state resolved molecular beam condensation |
| title | State-resolved studies of CO2 sticking to CO2 ice |
| title_full | State-resolved studies of CO2 sticking to CO2 ice |
| title_fullStr | State-resolved studies of CO2 sticking to CO2 ice |
| title_full_unstemmed | State-resolved studies of CO2 sticking to CO2 ice |
| title_short | State-resolved studies of CO2 sticking to CO2 ice |
| title_sort | state resolved studies of co2 sticking to co2 ice |
| topic | CO2 nu3 state resolved molecular beam condensation |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2023.1250711/full |
| work_keys_str_mv | AT charlottejansen stateresolvedstudiesofco2stickingtoco2ice AT ludobfjuurlink stateresolvedstudiesofco2stickingtoco2ice |