6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one
The title compound, C14H12N2O4, is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intramolecular N—H...O hydrogen bond. In the crystal, the molecules form in...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-10-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431462001384X |
| _version_ | 1818936826023378944 |
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| author | Uwe Böhme Sabine Fels |
| author_facet | Uwe Böhme Sabine Fels |
| author_sort | Uwe Böhme |
| collection | DOAJ |
| description | The title compound, C14H12N2O4, is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intramolecular N—H...O hydrogen bond. In the crystal, the molecules form inversion dimers via pairwise O—H...O hydrogen bonds. |
| first_indexed | 2024-12-20T05:42:14Z |
| format | Article |
| id | doaj.art-3cd33de3cd77467ca662832393f18593 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T05:42:14Z |
| publishDate | 2020-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-3cd33de3cd77467ca662832393f185932022-12-21T19:51:25ZengInternational Union of CrystallographyIUCrData2414-31462020-10-01510x20138410.1107/S241431462001384Xhb43676-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-oneUwe Böhme0Sabine Fels1Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyInstitut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyThe title compound, C14H12N2O4, is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intramolecular N—H...O hydrogen bond. In the crystal, the molecules form inversion dimers via pairwise O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S241431462001384Xcrystal structureschiff basetridentate ligand |
| spellingShingle | Uwe Böhme Sabine Fels 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one IUCrData crystal structure schiff base tridentate ligand |
| title | 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one |
| title_full | 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one |
| title_fullStr | 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one |
| title_full_unstemmed | 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one |
| title_short | 6-[(2-Hydroxy-5-methylanilino)methylidene]-4-nitrocyclohexa-2,4-dien-1-one |
| title_sort | 6 2 hydroxy 5 methylanilino methylidene 4 nitrocyclohexa 2 4 dien 1 one |
| topic | crystal structure schiff base tridentate ligand |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431462001384X |
| work_keys_str_mv | AT uwebohme 62hydroxy5methylanilinomethylidene4nitrocyclohexa24dien1one AT sabinefels 62hydroxy5methylanilinomethylidene4nitrocyclohexa24dien1one |