Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components

Abstract This study illustrates an innovative way to fabricate inkjet-printed tracks by sequential printing of Zn nanoparticle ink and curing ink for low temperature in situ chemical sintering. Employing chemical curing in place of standard sintering methods leads to the advantages of using flexible...

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Main Authors: Subimal Majee, Mikael C. F. Karlsson, Anurak Sawatdee, Mohammad Yusuf Mulla, Naveed ul Hassan Alvi, Valerio Beni, David Nilsson
Format: Article
Language:English
Published: Nature Portfolio 2021-07-01
Series:npj Flexible Electronics
Online Access:https://doi.org/10.1038/s41528-021-00111-1
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author Subimal Majee
Mikael C. F. Karlsson
Anurak Sawatdee
Mohammad Yusuf Mulla
Naveed ul Hassan Alvi
Valerio Beni
David Nilsson
author_facet Subimal Majee
Mikael C. F. Karlsson
Anurak Sawatdee
Mohammad Yusuf Mulla
Naveed ul Hassan Alvi
Valerio Beni
David Nilsson
author_sort Subimal Majee
collection DOAJ
description Abstract This study illustrates an innovative way to fabricate inkjet-printed tracks by sequential printing of Zn nanoparticle ink and curing ink for low temperature in situ chemical sintering. Employing chemical curing in place of standard sintering methods leads to the advantages of using flexible substrates that may not withstand the high thermal budgets of the standard methods. A general formulation engineering method is adopted to produce highly concentrated Zn ink which is cured by inkjet printing an over-layer of aqueous acetic acid which is the curing agent. The experimental results reveal that a narrow window of acid concentration of curing ink plays a crucial role in determining the electrical properties of the printed Zn nanoparticles. Highly conductive (~105 S m−1) and mechanically flexible printed Zn features are achieved. In addition, from systematic material characterization, we obtain an understanding of the curing mechanism. Finally, a touch sensor circuit is demonstrated involving all-Zn printed conductive tracks.
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spelling doaj.art-3ce6ee117e96409fb5033b13a0e0b0652022-12-21T21:21:42ZengNature Portfolionpj Flexible Electronics2397-46212021-07-01511810.1038/s41528-021-00111-1Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic componentsSubimal Majee0Mikael C. F. Karlsson1Anurak Sawatdee2Mohammad Yusuf Mulla3Naveed ul Hassan Alvi4Valerio Beni5David Nilsson6RISE Research Institutes of SwedenRISE Research Institutes of SwedenRISE Research Institutes of SwedenRISE Research Institutes of SwedenRISE Research Institutes of SwedenRISE Research Institutes of SwedenRISE Research Institutes of SwedenAbstract This study illustrates an innovative way to fabricate inkjet-printed tracks by sequential printing of Zn nanoparticle ink and curing ink for low temperature in situ chemical sintering. Employing chemical curing in place of standard sintering methods leads to the advantages of using flexible substrates that may not withstand the high thermal budgets of the standard methods. A general formulation engineering method is adopted to produce highly concentrated Zn ink which is cured by inkjet printing an over-layer of aqueous acetic acid which is the curing agent. The experimental results reveal that a narrow window of acid concentration of curing ink plays a crucial role in determining the electrical properties of the printed Zn nanoparticles. Highly conductive (~105 S m−1) and mechanically flexible printed Zn features are achieved. In addition, from systematic material characterization, we obtain an understanding of the curing mechanism. Finally, a touch sensor circuit is demonstrated involving all-Zn printed conductive tracks.https://doi.org/10.1038/s41528-021-00111-1
spellingShingle Subimal Majee
Mikael C. F. Karlsson
Anurak Sawatdee
Mohammad Yusuf Mulla
Naveed ul Hassan Alvi
Valerio Beni
David Nilsson
Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
npj Flexible Electronics
title Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
title_full Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
title_fullStr Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
title_full_unstemmed Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
title_short Low temperature chemical sintering of inkjet-printed Zn nanoparticles for highly conductive flexible electronic components
title_sort low temperature chemical sintering of inkjet printed zn nanoparticles for highly conductive flexible electronic components
url https://doi.org/10.1038/s41528-021-00111-1
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