Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery
Solid electrolytes with high ionic conductivity, high formability, and high electrochemical properties are required to improve the performance of all-solid-state sodium batteries. In this study, we focus on a combination of Na2.88Sb0.88W0.12S4 and NaI for preparing composite electrolytes Na2.88Sb0.8...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
The Electrochemical Society of Japan
2022-04-01
|
| Series: | Electrochemistry |
| Subjects: | |
| Online Access: | https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00016/_html/-char/en |
| _version_ | 1797969325636714496 |
|---|---|
| author | Takuma TAKAYANAGI Akira NASU Fumika TSUJI Atsushi SAKUDA Masahiro TATSUMISAGO Akitoshi HAYASHI |
| author_facet | Takuma TAKAYANAGI Akira NASU Fumika TSUJI Atsushi SAKUDA Masahiro TATSUMISAGO Akitoshi HAYASHI |
| author_sort | Takuma TAKAYANAGI |
| collection | DOAJ |
| description | Solid electrolytes with high ionic conductivity, high formability, and high electrochemical properties are required to improve the performance of all-solid-state sodium batteries. In this study, we focus on a combination of Na2.88Sb0.88W0.12S4 and NaI for preparing composite electrolytes Na2.88Sb0.88W0.12S4·xNaI, and investigate their crystal structures, microstructures, and electrochemical properties. NaI is uniformly dispersed in the composites without forming a solid solution with Na2.88Sb0.88W0.12S4. Na2.88Sb0.88W0.12S4·0.50NaI shows a high ionic conductivity of 3.6 × 10−2 S cm−1 after sintering at 275 °C for only 1.5 h. The charge-discharge characteristics of all-solid-state cells using the Na2.88Sb0.88W0.12S4·xNaI composite are also improved. |
| first_indexed | 2024-04-11T03:00:29Z |
| format | Article |
| id | doaj.art-3cf68a80cd9547d6928c19452286d8dc |
| institution | Directory Open Access Journal |
| issn | 2186-2451 |
| language | English |
| last_indexed | 2024-04-11T03:00:29Z |
| publishDate | 2022-04-01 |
| publisher | The Electrochemical Society of Japan |
| record_format | Article |
| series | Electrochemistry |
| spelling | doaj.art-3cf68a80cd9547d6928c19452286d8dc2023-01-02T14:08:04ZengThe Electrochemical Society of JapanElectrochemistry2186-24512022-04-0190404700504700510.5796/electrochemistry.22-00016electrochemistryMechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium BatteryTakuma TAKAYANAGI0Akira NASU1Fumika TSUJI2Atsushi SAKUDA3Masahiro TATSUMISAGO4Akitoshi HAYASHI5Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversityDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversityDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversityDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversityDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversityDepartment of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture UniversitySolid electrolytes with high ionic conductivity, high formability, and high electrochemical properties are required to improve the performance of all-solid-state sodium batteries. In this study, we focus on a combination of Na2.88Sb0.88W0.12S4 and NaI for preparing composite electrolytes Na2.88Sb0.88W0.12S4·xNaI, and investigate their crystal structures, microstructures, and electrochemical properties. NaI is uniformly dispersed in the composites without forming a solid solution with Na2.88Sb0.88W0.12S4. Na2.88Sb0.88W0.12S4·0.50NaI shows a high ionic conductivity of 3.6 × 10−2 S cm−1 after sintering at 275 °C for only 1.5 h. The charge-discharge characteristics of all-solid-state cells using the Na2.88Sb0.88W0.12S4·xNaI composite are also improved.https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00016/_html/-char/ensolid electrolyteall-solid-state sodium batterysulfidecomposite |
| spellingShingle | Takuma TAKAYANAGI Akira NASU Fumika TSUJI Atsushi SAKUDA Masahiro TATSUMISAGO Akitoshi HAYASHI Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery Electrochemistry solid electrolyte all-solid-state sodium battery sulfide composite |
| title | Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery |
| title_full | Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery |
| title_fullStr | Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery |
| title_full_unstemmed | Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery |
| title_short | Mechanochemically Prepared Highly Conductive Na2.88Sb0.88W0.12S4-NaI Composite Electrolytes for All-Solid-State Sodium Battery |
| title_sort | mechanochemically prepared highly conductive na2 88sb0 88w0 12s4 nai composite electrolytes for all solid state sodium battery |
| topic | solid electrolyte all-solid-state sodium battery sulfide composite |
| url | https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00016/_html/-char/en |
| work_keys_str_mv | AT takumatakayanagi mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery AT akiranasu mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery AT fumikatsuji mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery AT atsushisakuda mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery AT masahirotatsumisago mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery AT akitoshihayashi mechanochemicallypreparedhighlyconductivena288sb088w012s4naicompositeelectrolytesforallsolidstatesodiumbattery |