Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
Abstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the propert...
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Format: | Article |
Language: | English |
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Tsinghua University Press
2017-12-01
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Series: | Journal of Advanced Ceramics |
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Online Access: | http://link.springer.com/article/10.1007/s40145-017-0245-1 |
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author | Mohammed Abdulmunem Abdulhameed Mohd Hafiz Dzarfan Othman Haider Nadhom Azziz Al Joda Ahmad Fauzi Ismail Takeshi Matsuura Zawati Harun Mukhlis A. Rahman Mohd Hafiz Puteh Juhana Jaafar |
author_facet | Mohammed Abdulmunem Abdulhameed Mohd Hafiz Dzarfan Othman Haider Nadhom Azziz Al Joda Ahmad Fauzi Ismail Takeshi Matsuura Zawati Harun Mukhlis A. Rahman Mohd Hafiz Puteh Juhana Jaafar |
author_sort | Mohammed Abdulmunem Abdulhameed |
collection | DOAJ |
description | Abstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the properties of the hollow fibre membranes (gas permeation, mechanical strength, pore size, porosity, tortuosity, morphology, and contact angle) by the addition of alumina (Al2O3) to the pure kaolin with mono or multiparticle sizes. By varying the overall loading and particle size of alumina addition, different morphologies of the membranes were obtained due to the differences in the path lengths during phase inversion process for each solvent and nonsolvent exchange. The successful grafting with FAS was evidenced by the increase in contact angle from nearly equal to zero degree before grafting to 140° after grafting. Kaolin–alumina-4, one of the hollow fibres fabricated in this work, achieved a mean pore size of 0.25 μm with the bending strength of 96.4 MPa and high nitrogen permeance of 2.3×10-5 mol·m-2·Pa-1·s-1, which makes the hollow fibre most suitable for the membrane contactor application. |
first_indexed | 2024-03-12T06:38:59Z |
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id | doaj.art-3d1113080448483db21b3e4dbb741d98 |
institution | Directory Open Access Journal |
issn | 2226-4108 2227-8508 |
language | English |
last_indexed | 2024-03-12T06:38:59Z |
publishDate | 2017-12-01 |
publisher | Tsinghua University Press |
record_format | Article |
series | Journal of Advanced Ceramics |
spelling | doaj.art-3d1113080448483db21b3e4dbb741d982023-09-03T01:06:31ZengTsinghua University PressJournal of Advanced Ceramics2226-41082227-85082017-12-016433034010.1007/s40145-017-0245-1Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processesMohammed Abdulmunem Abdulhameed0Mohd Hafiz Dzarfan Othman1Haider Nadhom Azziz Al Joda2Ahmad Fauzi Ismail3Takeshi Matsuura4Zawati Harun5Mukhlis A. Rahman6Mohd Hafiz Puteh7Juhana Jaafar8Advanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Petroleum and Petrochemical Engineering, Engineering College, Kerbala UniversityAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Chemical and Biological Engineering, University of OttawaAdvanced Manufacturing & Materials Centre (AMMC), Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein Onn MalaysiaAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Environmental Engineering, Faculty of Civil Engineering, Universiti Teknologi Malaysia, UTMAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMAbstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the properties of the hollow fibre membranes (gas permeation, mechanical strength, pore size, porosity, tortuosity, morphology, and contact angle) by the addition of alumina (Al2O3) to the pure kaolin with mono or multiparticle sizes. By varying the overall loading and particle size of alumina addition, different morphologies of the membranes were obtained due to the differences in the path lengths during phase inversion process for each solvent and nonsolvent exchange. The successful grafting with FAS was evidenced by the increase in contact angle from nearly equal to zero degree before grafting to 140° after grafting. Kaolin–alumina-4, one of the hollow fibres fabricated in this work, achieved a mean pore size of 0.25 μm with the bending strength of 96.4 MPa and high nitrogen permeance of 2.3×10-5 mol·m-2·Pa-1·s-1, which makes the hollow fibre most suitable for the membrane contactor application.http://link.springer.com/article/10.1007/s40145-017-0245-1ceramic membrane contactorhollow fibrekaolinhydrophobic |
spellingShingle | Mohammed Abdulmunem Abdulhameed Mohd Hafiz Dzarfan Othman Haider Nadhom Azziz Al Joda Ahmad Fauzi Ismail Takeshi Matsuura Zawati Harun Mukhlis A. Rahman Mohd Hafiz Puteh Juhana Jaafar Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes Journal of Advanced Ceramics ceramic membrane contactor hollow fibre kaolin hydrophobic |
title | Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
title_full | Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
title_fullStr | Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
title_full_unstemmed | Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
title_short | Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
title_sort | fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes |
topic | ceramic membrane contactor hollow fibre kaolin hydrophobic |
url | http://link.springer.com/article/10.1007/s40145-017-0245-1 |
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