Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes

Abstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the propert...

Full description

Bibliographic Details
Main Authors: Mohammed Abdulmunem Abdulhameed, Mohd Hafiz Dzarfan Othman, Haider Nadhom Azziz Al Joda, Ahmad Fauzi Ismail, Takeshi Matsuura, Zawati Harun, Mukhlis A. Rahman, Mohd Hafiz Puteh, Juhana Jaafar
Format: Article
Language:English
Published: Tsinghua University Press 2017-12-01
Series:Journal of Advanced Ceramics
Subjects:
Online Access:http://link.springer.com/article/10.1007/s40145-017-0245-1
_version_ 1827837193905766400
author Mohammed Abdulmunem Abdulhameed
Mohd Hafiz Dzarfan Othman
Haider Nadhom Azziz Al Joda
Ahmad Fauzi Ismail
Takeshi Matsuura
Zawati Harun
Mukhlis A. Rahman
Mohd Hafiz Puteh
Juhana Jaafar
author_facet Mohammed Abdulmunem Abdulhameed
Mohd Hafiz Dzarfan Othman
Haider Nadhom Azziz Al Joda
Ahmad Fauzi Ismail
Takeshi Matsuura
Zawati Harun
Mukhlis A. Rahman
Mohd Hafiz Puteh
Juhana Jaafar
author_sort Mohammed Abdulmunem Abdulhameed
collection DOAJ
description Abstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the properties of the hollow fibre membranes (gas permeation, mechanical strength, pore size, porosity, tortuosity, morphology, and contact angle) by the addition of alumina (Al2O3) to the pure kaolin with mono or multiparticle sizes. By varying the overall loading and particle size of alumina addition, different morphologies of the membranes were obtained due to the differences in the path lengths during phase inversion process for each solvent and nonsolvent exchange. The successful grafting with FAS was evidenced by the increase in contact angle from nearly equal to zero degree before grafting to 140° after grafting. Kaolin–alumina-4, one of the hollow fibres fabricated in this work, achieved a mean pore size of 0.25 μm with the bending strength of 96.4 MPa and high nitrogen permeance of 2.3×10-5 mol·m-2·Pa-1·s-1, which makes the hollow fibre most suitable for the membrane contactor application.
first_indexed 2024-03-12T06:38:59Z
format Article
id doaj.art-3d1113080448483db21b3e4dbb741d98
institution Directory Open Access Journal
issn 2226-4108
2227-8508
language English
last_indexed 2024-03-12T06:38:59Z
publishDate 2017-12-01
publisher Tsinghua University Press
record_format Article
series Journal of Advanced Ceramics
spelling doaj.art-3d1113080448483db21b3e4dbb741d982023-09-03T01:06:31ZengTsinghua University PressJournal of Advanced Ceramics2226-41082227-85082017-12-016433034010.1007/s40145-017-0245-1Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processesMohammed Abdulmunem Abdulhameed0Mohd Hafiz Dzarfan Othman1Haider Nadhom Azziz Al Joda2Ahmad Fauzi Ismail3Takeshi Matsuura4Zawati Harun5Mukhlis A. Rahman6Mohd Hafiz Puteh7Juhana Jaafar8Advanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Petroleum and Petrochemical Engineering, Engineering College, Kerbala UniversityAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Chemical and Biological Engineering, University of OttawaAdvanced Manufacturing & Materials Centre (AMMC), Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein Onn MalaysiaAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMDepartment of Environmental Engineering, Faculty of Civil Engineering, Universiti Teknologi Malaysia, UTMAdvanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, UTMAbstract Affordable hydrophobic hollow fibre membranes were prepared using kaolin and alumina based ceramic powders via a combined phase inversion and sintering technique, followed by a grafting with fluoroalkylsilane (FAS). The crux of the matter in this paper is to study the changes in the properties of the hollow fibre membranes (gas permeation, mechanical strength, pore size, porosity, tortuosity, morphology, and contact angle) by the addition of alumina (Al2O3) to the pure kaolin with mono or multiparticle sizes. By varying the overall loading and particle size of alumina addition, different morphologies of the membranes were obtained due to the differences in the path lengths during phase inversion process for each solvent and nonsolvent exchange. The successful grafting with FAS was evidenced by the increase in contact angle from nearly equal to zero degree before grafting to 140° after grafting. Kaolin–alumina-4, one of the hollow fibres fabricated in this work, achieved a mean pore size of 0.25 μm with the bending strength of 96.4 MPa and high nitrogen permeance of 2.3×10-5 mol·m-2·Pa-1·s-1, which makes the hollow fibre most suitable for the membrane contactor application.http://link.springer.com/article/10.1007/s40145-017-0245-1ceramic membrane contactorhollow fibrekaolinhydrophobic
spellingShingle Mohammed Abdulmunem Abdulhameed
Mohd Hafiz Dzarfan Othman
Haider Nadhom Azziz Al Joda
Ahmad Fauzi Ismail
Takeshi Matsuura
Zawati Harun
Mukhlis A. Rahman
Mohd Hafiz Puteh
Juhana Jaafar
Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
Journal of Advanced Ceramics
ceramic membrane contactor
hollow fibre
kaolin
hydrophobic
title Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
title_full Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
title_fullStr Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
title_full_unstemmed Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
title_short Fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
title_sort fabrication and characterization of affordable hydrophobic ceramic hollow fibre membrane for contacting processes
topic ceramic membrane contactor
hollow fibre
kaolin
hydrophobic
url http://link.springer.com/article/10.1007/s40145-017-0245-1
work_keys_str_mv AT mohammedabdulmunemabdulhameed fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT mohdhafizdzarfanothman fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT haidernadhomazzizaljoda fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT ahmadfauziismail fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT takeshimatsuura fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT zawatiharun fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT mukhlisarahman fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT mohdhafizputeh fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses
AT juhanajaafar fabricationandcharacterizationofaffordablehydrophobicceramichollowfibremembraneforcontactingprocesses