5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1)
The asymmetric unit of the title compound, 2C10H11N2+·2C3H3O4−·C3H4O4, consists of one 5-amino-6-methylquinolin-1-ium cation, one hydrogen malonate (2-carboxyacetate) anion and one-half molecule of malonic acid which lies on a twofold rotation axis. The quinoline ring sys...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813002547 |
| _version_ | 1798030928042262528 |
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| author | Ibrahim Abdul Razak Suhana Arshad Nuridayanti Che Khalib Kaliyaperumal Thanigaimani |
| author_facet | Ibrahim Abdul Razak Suhana Arshad Nuridayanti Che Khalib Kaliyaperumal Thanigaimani |
| author_sort | Ibrahim Abdul Razak |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, 2C10H11N2+·2C3H3O4−·C3H4O4, consists of one 5-amino-6-methylquinolin-1-ium cation, one hydrogen malonate (2-carboxyacetate) anion and one-half molecule of malonic acid which lies on a twofold rotation axis. The quinoline ring system is essentially planar, with a maximum deviation of 0.062 (2) Å for all non-H atoms. In the anion, an intramolecular O—H...O hydrogen bond generates an S(6) ring. In the crystal, the components are linked via N—H...O and O—H...O hydrogen bonds into layers parallel to the ac plane. The crystal structure also features weak C—H...O hydrogen bonds and a π–π stacking interaction with a centroid–centroid distance of 3.8189 (10) Å. |
| first_indexed | 2024-04-11T19:47:57Z |
| format | Article |
| id | doaj.art-3d1f42c5c4de4f2b9b01127ce2ee5b79 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:47:57Z |
| publishDate | 2013-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3d1f42c5c4de4f2b9b01127ce2ee5b792022-12-22T04:06:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693o319o32010.1107/S16005368130025475-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1)Ibrahim Abdul RazakSuhana ArshadNuridayanti Che KhalibKaliyaperumal ThanigaimaniThe asymmetric unit of the title compound, 2C10H11N2+·2C3H3O4−·C3H4O4, consists of one 5-amino-6-methylquinolin-1-ium cation, one hydrogen malonate (2-carboxyacetate) anion and one-half molecule of malonic acid which lies on a twofold rotation axis. The quinoline ring system is essentially planar, with a maximum deviation of 0.062 (2) Å for all non-H atoms. In the anion, an intramolecular O—H...O hydrogen bond generates an S(6) ring. In the crystal, the components are linked via N—H...O and O—H...O hydrogen bonds into layers parallel to the ac plane. The crystal structure also features weak C—H...O hydrogen bonds and a π–π stacking interaction with a centroid–centroid distance of 3.8189 (10) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813002547 |
| spellingShingle | Ibrahim Abdul Razak Suhana Arshad Nuridayanti Che Khalib Kaliyaperumal Thanigaimani 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) Acta Crystallographica Section E |
| title | 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) |
| title_full | 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) |
| title_fullStr | 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) |
| title_full_unstemmed | 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) |
| title_short | 5-Amino-6-methylquinolin-1-ium hydrogen malonate–malonic acid (2/1) |
| title_sort | 5 amino 6 methylquinolin 1 ium hydrogen malonate 8211 malonic acid 2 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813002547 |
| work_keys_str_mv | AT ibrahimabdulrazak 5amino6methylquinolin1iumhydrogenmalonate8211malonicacid21 AT suhanaarshad 5amino6methylquinolin1iumhydrogenmalonate8211malonicacid21 AT nuridayantichekhalib 5amino6methylquinolin1iumhydrogenmalonate8211malonicacid21 AT kaliyaperumalthanigaimani 5amino6methylquinolin1iumhydrogenmalonate8211malonicacid21 |