Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate
In the title compound, (C13H11N2)2[Zn(C7H3NO4)2]·3H2O, the ZnII ion is six-coordinated with the N4O2 donor set being a distorted octahedron through two almost perpendicular (r.m.s. deviation of ligand atoms from the mean plane is 0.057 Å) tridentate pyridine-2...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812005764 |
| _version_ | 1798024394901028864 |
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| author | M. Mirzaei H. Eshtiagh-Hosseini E. Eydizadeh Z. Yousefi K. Molčanov |
| author_facet | M. Mirzaei H. Eshtiagh-Hosseini E. Eydizadeh Z. Yousefi K. Molčanov |
| author_sort | M. Mirzaei |
| collection | DOAJ |
| description | In the title compound, (C13H11N2)2[Zn(C7H3NO4)2]·3H2O, the ZnII ion is six-coordinated with the N4O2 donor set being a distorted octahedron through two almost perpendicular (r.m.s. deviation of ligand atoms from the mean plane is 0.057 Å) tridentate pyridine-2,6-dicarboxylate ligands [dihedral angle between the ligands = 86.06 (4)°]. The charge is compensated by two 9-aminoacridinium cations protonated on the ring N atom. A variety of intermolecular contacts, such as ion–ion, N—H...O and O—H...O hydrogen bonds, and π–π stacking [centroid–centroid distances = 3.4907 (9)–4.1128 (8) Å], between cations and between anions, play important roles in the formation of the three-dimensional network. |
| first_indexed | 2024-04-11T18:01:42Z |
| format | Article |
| id | doaj.art-3d2ad225bb0e4b9f8a864ea78fcbbdc2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:01:42Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3d2ad225bb0e4b9f8a864ea78fcbbdc22022-12-22T04:10:27ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m355m35610.1107/S1600536812005764Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrateM. MirzaeiH. Eshtiagh-HosseiniE. EydizadehZ. YousefiK. MolčanovIn the title compound, (C13H11N2)2[Zn(C7H3NO4)2]·3H2O, the ZnII ion is six-coordinated with the N4O2 donor set being a distorted octahedron through two almost perpendicular (r.m.s. deviation of ligand atoms from the mean plane is 0.057 Å) tridentate pyridine-2,6-dicarboxylate ligands [dihedral angle between the ligands = 86.06 (4)°]. The charge is compensated by two 9-aminoacridinium cations protonated on the ring N atom. A variety of intermolecular contacts, such as ion–ion, N—H...O and O—H...O hydrogen bonds, and π–π stacking [centroid–centroid distances = 3.4907 (9)–4.1128 (8) Å], between cations and between anions, play important roles in the formation of the three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812005764 |
| spellingShingle | M. Mirzaei H. Eshtiagh-Hosseini E. Eydizadeh Z. Yousefi K. Molčanov Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate Acta Crystallographica Section E |
| title | Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate |
| title_full | Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate |
| title_fullStr | Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate |
| title_full_unstemmed | Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate |
| title_short | Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)zincate(II) trihydrate |
| title_sort | bis 9 aminoacridinium bis pyridine 2 6 dicarboxylato zincate ii trihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812005764 |
| work_keys_str_mv | AT mmirzaei bis9aminoacridiniumbispyridine26dicarboxylatozincateiitrihydrate AT heshtiaghhosseini bis9aminoacridiniumbispyridine26dicarboxylatozincateiitrihydrate AT eeydizadeh bis9aminoacridiniumbispyridine26dicarboxylatozincateiitrihydrate AT zyousefi bis9aminoacridiniumbispyridine26dicarboxylatozincateiitrihydrate AT kmolamp269anov bis9aminoacridiniumbispyridine26dicarboxylatozincateiitrihydrate |