[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)
In the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine l...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681202884X |
| _version_ | 1818958862067171328 |
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| author | Aliakbar Dehno Khalaji Bahram Bahramian Khadijeh Jafari Karla Fejfarová Michal Dušek |
| author_facet | Aliakbar Dehno Khalaji Bahram Bahramian Khadijeh Jafari Karla Fejfarová Michal Dušek |
| author_sort | Aliakbar Dehno Khalaji |
| collection | DOAJ |
| description | In the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å]. |
| first_indexed | 2024-12-20T11:32:29Z |
| format | Article |
| id | doaj.art-3d4d19c80d1848599767151e878630c2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:32:29Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3d4d19c80d1848599767151e878630c22022-12-21T19:42:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m1001m100210.1107/S160053681202884X[4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I)Aliakbar Dehno KhalajiBahram BahramianKhadijeh JafariKarla FejfarováMichal DušekIn the title compound, [CuI(C12H9BrN2)(C18H15P)], the CuI ion is bonded to one I atom, one triphenylphosphane P atom and two N atoms of the diimine ligand in a distorted tetrahedral geometry. The Schiff base acts as a chelating ligand and coordinates to the CuI atom via two N atoms. In the diimine ligand, the dihedral angle between the pyridine and bromophenyl rings is 19.2 (2)°. In the crystal, molecules are connected by π–π stacking interactions between inversion-related pyridine rings [centroid–centroid distance = 3.404 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S160053681202884X |
| spellingShingle | Aliakbar Dehno Khalaji Bahram Bahramian Khadijeh Jafari Karla Fejfarová Michal Dušek [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) Acta Crystallographica Section E |
| title | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) |
| title_full | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) |
| title_fullStr | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) |
| title_full_unstemmed | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) |
| title_short | [4-Bromo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′]iodido(triphenylphosphane-κP)copper(I) |
| title_sort | 4 bromo n pyridin 2 ylmethylidene aniline amp 954 2n n amp 8242 iodido triphenylphosphane amp 954 p copper i |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681202884X |
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