Bis(2,6-diaminopyridinium) tartrate monohydrate
In the title compound, 2C5H8N3+·C4H4O62−·H2O, the two cations are essentially planar [maximum deviations = 0.023 (1) and 0.026 (1) Å]. In one of the cations, the protonated N atom and one of the amino grou...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809044663 |
| _version_ | 1828854824067661824 |
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| author | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Jia Hao Goh Hoong-Kun Fun |
| author_facet | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Jia Hao Goh Hoong-Kun Fun |
| author_sort | Mohammad T. M. Al-Dajani |
| collection | DOAJ |
| description | In the title compound, 2C5H8N3+·C4H4O62−·H2O, the two cations are essentially planar [maximum deviations = 0.023 (1) and 0.026 (1) Å]. In one of the cations, the protonated N atom and one of the amino group H atoms are hydrogen bonded to one of the carboxyl groups of the dianion through a pair of N—H...O hydrogen bonds, forming an R22(8) ring motif. In the crystal structure, the tartrate anions and water molecules are linked into chains along the c axis by intermolecular O—H...O and C—H...O hydrogen bonds. The cations further link the anions and water molecules into a three-dimensional extended structure by a network of N—H...O hydrogen bonds. The crystal structure is also stabilized by weak intermolecular π–π interactions [centroid–centroid distance = 3.6950 (6) Å]. |
| first_indexed | 2024-12-13T00:41:01Z |
| format | Article |
| id | doaj.art-3d53091833fe43a9a181686c5ccfd03f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:41:01Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3d53091833fe43a9a181686c5ccfd03f2022-12-22T00:05:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511o2939o294010.1107/S1600536809044663Bis(2,6-diaminopyridinium) tartrate monohydrateMohammad T. M. Al-DajaniHassan H. AbdallahNornisah MohamedJia Hao GohHoong-Kun FunIn the title compound, 2C5H8N3+·C4H4O62−·H2O, the two cations are essentially planar [maximum deviations = 0.023 (1) and 0.026 (1) Å]. In one of the cations, the protonated N atom and one of the amino group H atoms are hydrogen bonded to one of the carboxyl groups of the dianion through a pair of N—H...O hydrogen bonds, forming an R22(8) ring motif. In the crystal structure, the tartrate anions and water molecules are linked into chains along the c axis by intermolecular O—H...O and C—H...O hydrogen bonds. The cations further link the anions and water molecules into a three-dimensional extended structure by a network of N—H...O hydrogen bonds. The crystal structure is also stabilized by weak intermolecular π–π interactions [centroid–centroid distance = 3.6950 (6) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809044663 |
| spellingShingle | Mohammad T. M. Al-Dajani Hassan H. Abdallah Nornisah Mohamed Jia Hao Goh Hoong-Kun Fun Bis(2,6-diaminopyridinium) tartrate monohydrate Acta Crystallographica Section E |
| title | Bis(2,6-diaminopyridinium) tartrate monohydrate |
| title_full | Bis(2,6-diaminopyridinium) tartrate monohydrate |
| title_fullStr | Bis(2,6-diaminopyridinium) tartrate monohydrate |
| title_full_unstemmed | Bis(2,6-diaminopyridinium) tartrate monohydrate |
| title_short | Bis(2,6-diaminopyridinium) tartrate monohydrate |
| title_sort | bis 2 6 diaminopyridinium tartrate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809044663 |
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