Mechanical properties of geopolymer mortars in relation to their porous structure

This research dealt with metakaolinite geopolymers of various textures controlled by the addition of a quartz sand in a range of 0–93 wt.%. Mechanical properties were measured to quantify the impact of changing composition on the specimen structure, aimed to the mixture optimizing. The compressive a...

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Main Author: Michaela Steinerova
Format: Article
Language:English
Published: University of Chemistry and Technology, Prague 2011-12-01
Series:Ceramics-Silikáty
Subjects:
Online Access:http://www.ceramics-silikaty.cz/2011/pdf/2011_04_362.pdf
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author Michaela Steinerova
author_facet Michaela Steinerova
author_sort Michaela Steinerova
collection DOAJ
description This research dealt with metakaolinite geopolymers of various textures controlled by the addition of a quartz sand in a range of 0–93 wt.%. Mechanical properties were measured to quantify the impact of changing composition on the specimen structure, aimed to the mixture optimizing. The compressive and flexural strengths, Young’s modulus and frost resistance were compared with structure parameters determined by mercury porosimetry. The resulting relations are discussed revealing varying control plots modifying the strengths and frost resistance. The existence of an interfacial transition zone caused by the interaction between the quartz aggregates and the geopolymer was verified to be positively affecting the composite strengths. It has been found that the material of the best mechanical properties underwent the maximal densification of the sand aggregates causing the approaching on the shortest distance with the condition of entirely coating by geopolymer gel. In this manner, the highest interface participation is represented on the composite structure. Besides the high strength, freezing resistance was conditioned by an at least 20% content (within the total porosity) of 1-8 μm large mesopores.
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spelling doaj.art-3d6deda05cf443eab8e24ac4f38046f72022-12-22T02:50:57ZengUniversity of Chemistry and Technology, PragueCeramics-Silikáty0862-54681804-58472011-12-01554362372Mechanical properties of geopolymer mortars in relation to their porous structureMichaela SteinerovaThis research dealt with metakaolinite geopolymers of various textures controlled by the addition of a quartz sand in a range of 0–93 wt.%. Mechanical properties were measured to quantify the impact of changing composition on the specimen structure, aimed to the mixture optimizing. The compressive and flexural strengths, Young’s modulus and frost resistance were compared with structure parameters determined by mercury porosimetry. The resulting relations are discussed revealing varying control plots modifying the strengths and frost resistance. The existence of an interfacial transition zone caused by the interaction between the quartz aggregates and the geopolymer was verified to be positively affecting the composite strengths. It has been found that the material of the best mechanical properties underwent the maximal densification of the sand aggregates causing the approaching on the shortest distance with the condition of entirely coating by geopolymer gel. In this manner, the highest interface participation is represented on the composite structure. Besides the high strength, freezing resistance was conditioned by an at least 20% content (within the total porosity) of 1-8 μm large mesopores.http://www.ceramics-silikaty.cz/2011/pdf/2011_04_362.pdfGeopolymersMechanical propertiesFrost resistancePore-size distributionITZ
spellingShingle Michaela Steinerova
Mechanical properties of geopolymer mortars in relation to their porous structure
Ceramics-Silikáty
Geopolymers
Mechanical properties
Frost resistance
Pore-size distribution
ITZ
title Mechanical properties of geopolymer mortars in relation to their porous structure
title_full Mechanical properties of geopolymer mortars in relation to their porous structure
title_fullStr Mechanical properties of geopolymer mortars in relation to their porous structure
title_full_unstemmed Mechanical properties of geopolymer mortars in relation to their porous structure
title_short Mechanical properties of geopolymer mortars in relation to their porous structure
title_sort mechanical properties of geopolymer mortars in relation to their porous structure
topic Geopolymers
Mechanical properties
Frost resistance
Pore-size distribution
ITZ
url http://www.ceramics-silikaty.cz/2011/pdf/2011_04_362.pdf
work_keys_str_mv AT michaelasteinerova mechanicalpropertiesofgeopolymermortarsinrelationtotheirporousstructure