Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells

Amorphous silicon (a-Si:H) / micro-crystalline silicon (μc-Si:H), "micromorph" tandem solar cells have been investigated using a detailed electrical - optical model. Although such a tandem has good light absorption over the entire visible spectrum, the a-Si:H top cell suffers from strong l...

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Main Authors: P. Chatterjee, P. Roca i Cabarrocas
Format: Article
Language:English
Published: AIP Publishing LLC 2018-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5005114
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author P. Chatterjee
P. Roca i Cabarrocas
author_facet P. Chatterjee
P. Roca i Cabarrocas
author_sort P. Chatterjee
collection DOAJ
description Amorphous silicon (a-Si:H) / micro-crystalline silicon (μc-Si:H), "micromorph" tandem solar cells have been investigated using a detailed electrical - optical model. Although such a tandem has good light absorption over the entire visible spectrum, the a-Si:H top cell suffers from strong light-induced degradation (LID). To improve matters, we have replaced a-Si:H by hydrogenated polymorphous silicon (pm-Si:H), a nano-structured silicon thin film with lower LID than a-Si:H. But the latter’s low current carrying capacity necessitates a thicker top cell for current-matching, again leading to LID problems. The solution is to introduce a suitable intermediate reflector (IR) at the junction between the sub-cells, to concentrate light of the shorter visible wavelengths into the top cell. Here we assess the suitability of N-type micro-crystalline silicon oxide (μc-SiOx:H) as an IR. The sensitivity of the solar cell performance to the complex refractive index, thickness and texture of such a reflector is studied. We conclude that N-μc-SiOx:H does concentrate light into the top sub-cell, thus reducing its required thickness for current-matching. However the IR also reflects light right out of the device; so that the initial efficiency suffers. The advantage of such an IR is ultimately seen in the stabilized state since the LID of a thin top cell is low. We also find that for high stabilized efficiencies, the IR should be flat (having no texture of its own). Our study indicates that we may expect to reach 15% stable tandem micromorph efficiency.
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spelling doaj.art-3d76754f4325489ea19fd6d0b9f977af2022-12-22T00:49:50ZengAIP Publishing LLCAIP Advances2158-32262018-01-0181015115015115-1410.1063/1.5005114103712ADVInfluence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cellsP. Chatterjee0P. Roca i Cabarrocas1Laboratoire de Physique des Interfaces et des Couches Minces, CNRS, Ecole Polytechnique, Université Paris-Saclay, 91128 Palaiseau, FranceLaboratoire de Physique des Interfaces et des Couches Minces, CNRS, Ecole Polytechnique, Université Paris-Saclay, 91128 Palaiseau, FranceAmorphous silicon (a-Si:H) / micro-crystalline silicon (μc-Si:H), "micromorph" tandem solar cells have been investigated using a detailed electrical - optical model. Although such a tandem has good light absorption over the entire visible spectrum, the a-Si:H top cell suffers from strong light-induced degradation (LID). To improve matters, we have replaced a-Si:H by hydrogenated polymorphous silicon (pm-Si:H), a nano-structured silicon thin film with lower LID than a-Si:H. But the latter’s low current carrying capacity necessitates a thicker top cell for current-matching, again leading to LID problems. The solution is to introduce a suitable intermediate reflector (IR) at the junction between the sub-cells, to concentrate light of the shorter visible wavelengths into the top cell. Here we assess the suitability of N-type micro-crystalline silicon oxide (μc-SiOx:H) as an IR. The sensitivity of the solar cell performance to the complex refractive index, thickness and texture of such a reflector is studied. We conclude that N-μc-SiOx:H does concentrate light into the top sub-cell, thus reducing its required thickness for current-matching. However the IR also reflects light right out of the device; so that the initial efficiency suffers. The advantage of such an IR is ultimately seen in the stabilized state since the LID of a thin top cell is low. We also find that for high stabilized efficiencies, the IR should be flat (having no texture of its own). Our study indicates that we may expect to reach 15% stable tandem micromorph efficiency.http://dx.doi.org/10.1063/1.5005114
spellingShingle P. Chatterjee
P. Roca i Cabarrocas
Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
AIP Advances
title Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
title_full Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
title_fullStr Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
title_full_unstemmed Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
title_short Influence of N-type μc-SiOx:H intermediate reflector and top cell material properties on the electrical performance of “micromorph” tandem solar cells
title_sort influence of n type μc siox h intermediate reflector and top cell material properties on the electrical performance of micromorph tandem solar cells
url http://dx.doi.org/10.1063/1.5005114
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