Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses

The nature of depth distribution of soil organic carbon (SOC) was examined in 85 soils across New South Wales with the working hypothesis that the depth distribution of SOC is controlled by processes that vary with depth in the profile. Mathematical functions were fitted to 85 profiles of SOC with S...

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Main Authors: Brian W. Murphy, Brian R. Wilson, Terry Koen
Format: Article
Language:English
Published: MDPI AG 2019-07-01
Series:Soil Systems
Subjects:
Online Access:https://www.mdpi.com/2571-8789/3/3/46
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author Brian W. Murphy
Brian R. Wilson
Terry Koen
author_facet Brian W. Murphy
Brian R. Wilson
Terry Koen
author_sort Brian W. Murphy
collection DOAJ
description The nature of depth distribution of soil organic carbon (SOC) was examined in 85 soils across New South Wales with the working hypothesis that the depth distribution of SOC is controlled by processes that vary with depth in the profile. Mathematical functions were fitted to 85 profiles of SOC with SOC values at depth intervals typically of 0−5, 5−10, 10−20, 20−30, 30−40, 40−50, 50−60, 60−70, 70−80, 80−90 and 90−100 cm. The functions fitted included exponential functions of the form SOC = A exp (Bz); SOC = A + B exp (Cz) as well as two phase exponential functions of the form SOC = A + B exp (Cz) + D exp (Ez). Other functions fitted included functions where the depth was a power exponent or an inverse term in a function. The universally best-fitting function was the exponential function SOC = A + B exp (Cz). When fitted, the most successful function was the two-phase exponential, but in several cases this function could not be fitted because of the large number of terms in the function. Semi-log plots of log values of the SOC against soil depth were also fitted to detect changes in the mathematical relationships between SOC and soil depth. These were hypothesized to represent changes in dominant soil processes at various depths. The success of the exponential function with an added constant, the two-phase exponential functions, and the demonstration of different phases within the semi-log plots confirmed our hypothesis that different processes were operating at different depths to control the depth distributions of SOC, there being a surface component, and deeper soil component. Several SOC profiles demonstrated specific features that are potentially important for the management of SOC profiles in soils. Woodland and to lesser extent pasture soils had a definite near surface zone within the SOC profile, indicating the addition of surface materials and high rates of fine root turnover. This zone was much less evident under cropping.
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spelling doaj.art-3da49206e9574d57bad1e57c4e88e81d2022-12-21T19:17:41ZengMDPI AGSoil Systems2571-87892019-07-01334610.3390/soilsystems3030046soilsystems3030046Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land UsesBrian W. Murphy0Brian R. Wilson1Terry Koen2NSW Office of Environment and Heritage, P.O. Box 445, Cowra, NSW 2794, AustraliaSchool of Environmental and Rural Sciences, University of New England, Armidale, NSW 2351, AustraliaNSW Office of Environment and Heritage, P.O. Box 445, Cowra, NSW 2794, AustraliaThe nature of depth distribution of soil organic carbon (SOC) was examined in 85 soils across New South Wales with the working hypothesis that the depth distribution of SOC is controlled by processes that vary with depth in the profile. Mathematical functions were fitted to 85 profiles of SOC with SOC values at depth intervals typically of 0−5, 5−10, 10−20, 20−30, 30−40, 40−50, 50−60, 60−70, 70−80, 80−90 and 90−100 cm. The functions fitted included exponential functions of the form SOC = A exp (Bz); SOC = A + B exp (Cz) as well as two phase exponential functions of the form SOC = A + B exp (Cz) + D exp (Ez). Other functions fitted included functions where the depth was a power exponent or an inverse term in a function. The universally best-fitting function was the exponential function SOC = A + B exp (Cz). When fitted, the most successful function was the two-phase exponential, but in several cases this function could not be fitted because of the large number of terms in the function. Semi-log plots of log values of the SOC against soil depth were also fitted to detect changes in the mathematical relationships between SOC and soil depth. These were hypothesized to represent changes in dominant soil processes at various depths. The success of the exponential function with an added constant, the two-phase exponential functions, and the demonstration of different phases within the semi-log plots confirmed our hypothesis that different processes were operating at different depths to control the depth distributions of SOC, there being a surface component, and deeper soil component. Several SOC profiles demonstrated specific features that are potentially important for the management of SOC profiles in soils. Woodland and to lesser extent pasture soils had a definite near surface zone within the SOC profile, indicating the addition of surface materials and high rates of fine root turnover. This zone was much less evident under cropping.https://www.mdpi.com/2571-8789/3/3/46soil organic carbondepth distributionmathematical functionsprocessesland management
spellingShingle Brian W. Murphy
Brian R. Wilson
Terry Koen
Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
Soil Systems
soil organic carbon
depth distribution
mathematical functions
processes
land management
title Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
title_full Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
title_fullStr Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
title_full_unstemmed Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
title_short Mathematical Functions to Model the Depth Distribution of Soil Organic Carbon in a Range of Soils from New South Wales, Australia under Different Land Uses
title_sort mathematical functions to model the depth distribution of soil organic carbon in a range of soils from new south wales australia under different land uses
topic soil organic carbon
depth distribution
mathematical functions
processes
land management
url https://www.mdpi.com/2571-8789/3/3/46
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