Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption

The combination of solid and liquid sorption media for thermal energy storage has been explored in order to improve heat flow as well as storage capacity with respect to the incomplete space-filling of closely packed solid sorbents. Three scenarios were elucidated from which in two cases the liquid/...

Full description

Bibliographic Details
Main Authors: Kristijan Krekić, Rudolf Pietschnig
Format: Article
Language:English
Published: Taylor & Francis Group 2019-05-01
Series:International Journal of Sustainable Energy
Subjects:
Online Access:http://dx.doi.org/10.1080/14786451.2018.1536660
_version_ 1797680347532492800
author Kristijan Krekić
Rudolf Pietschnig
author_facet Kristijan Krekić
Rudolf Pietschnig
author_sort Kristijan Krekić
collection DOAJ
description The combination of solid and liquid sorption media for thermal energy storage has been explored in order to improve heat flow as well as storage capacity with respect to the incomplete space-filling of closely packed solid sorbents. Three scenarios were elucidated from which in two cases the liquid/solid combinations perform worse than the neat liquid or solid and a third scenario where the combination performs better than the separate sorbents. We identified a mixture of zeolite 13XBF with tripropylene glycol as an example for such a superior combination showing a similar adsorption curve over time as the pure zeolite or glycol. After complete saturation of the zeolite in the mixture, glycol continues to absorb water, thereby increasing the overall capacity of the system. We identified a low direct attractive interaction (dipolar and dispersive) of the liquid sorbent (tripropylene glycol) with the solid sorbent (zeolite 13XBF) as a prerequisite for improved performance.
first_indexed 2024-03-11T23:28:41Z
format Article
id doaj.art-3db6607d3e7a41cb812d1c53fd79f6e7
institution Directory Open Access Journal
issn 1478-6451
1478-646X
language English
last_indexed 2024-03-11T23:28:41Z
publishDate 2019-05-01
publisher Taylor & Francis Group
record_format Article
series International Journal of Sustainable Energy
spelling doaj.art-3db6607d3e7a41cb812d1c53fd79f6e72023-09-20T10:33:45ZengTaylor & Francis GroupInternational Journal of Sustainable Energy1478-64511478-646X2019-05-0138548649210.1080/14786451.2018.15366601536660Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorptionKristijan Krekić0Rudolf Pietschnig1Universität KasselUniversität KasselThe combination of solid and liquid sorption media for thermal energy storage has been explored in order to improve heat flow as well as storage capacity with respect to the incomplete space-filling of closely packed solid sorbents. Three scenarios were elucidated from which in two cases the liquid/solid combinations perform worse than the neat liquid or solid and a third scenario where the combination performs better than the separate sorbents. We identified a mixture of zeolite 13XBF with tripropylene glycol as an example for such a superior combination showing a similar adsorption curve over time as the pure zeolite or glycol. After complete saturation of the zeolite in the mixture, glycol continues to absorb water, thereby increasing the overall capacity of the system. We identified a low direct attractive interaction (dipolar and dispersive) of the liquid sorbent (tripropylene glycol) with the solid sorbent (zeolite 13XBF) as a prerequisite for improved performance.http://dx.doi.org/10.1080/14786451.2018.1536660sorptionheat storagethermal energyzeoliteglycolgravimetry
spellingShingle Kristijan Krekić
Rudolf Pietschnig
Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
International Journal of Sustainable Energy
sorption
heat storage
thermal energy
zeolite
glycol
gravimetry
title Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
title_full Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
title_fullStr Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
title_full_unstemmed Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
title_short Exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
title_sort exploring storage capacity in thermal energy storage using a combination of solid and liquid desiccant sorption media for water sorption
topic sorption
heat storage
thermal energy
zeolite
glycol
gravimetry
url http://dx.doi.org/10.1080/14786451.2018.1536660
work_keys_str_mv AT kristijankrekic exploringstoragecapacityinthermalenergystorageusingacombinationofsolidandliquiddesiccantsorptionmediaforwatersorption
AT rudolfpietschnig exploringstoragecapacityinthermalenergystorageusingacombinationofsolidandliquiddesiccantsorptionmediaforwatersorption