Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation

Membrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a sui...

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Main Authors: Lies Eykens, Klaus Rose, Marjorie Dubreuil, Kristien De Sitter, Chris Dotremont, Luc Pinoy, Bart Van der Bruggen
Format: Article
Language:English
Published: MDPI AG 2017-06-01
Series:Applied Sciences
Subjects:
Online Access:http://www.mdpi.com/2076-3417/7/6/637
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author Lies Eykens
Klaus Rose
Marjorie Dubreuil
Kristien De Sitter
Chris Dotremont
Luc Pinoy
Bart Van der Bruggen
author_facet Lies Eykens
Klaus Rose
Marjorie Dubreuil
Kristien De Sitter
Chris Dotremont
Luc Pinoy
Bart Van der Bruggen
author_sort Lies Eykens
collection DOAJ
description Membrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a suitable structure for membrane distillation was modified using available hydrophobic coatings using ORMOCER® technology to obtain a hydrophobic membrane that can be applied in membrane distillation. The surface modification was performed using a selection of different components, concentrations, and application methods. The resulting membranes can have two hydrophobic surfaces or a hydrophobic and hydrophilic surface depending on the application method. An extensive characterization procedure confirmed the suitability of the coating technique and the obtained membranes for membrane distillation. The surface contact angle of water could be increased from 27° up to 110°, and fluxes comparable to membranes commonly used for membrane distillation were achieved under similar process conditions. A 100 h test demonstrated the stability of the coating and the importance of using sufficiently stable base membranes.
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spelling doaj.art-3dceb45b6d9648a08e54468c988937ec2022-12-22T03:56:24ZengMDPI AGApplied Sciences2076-34172017-06-017663710.3390/app7060637app7060637Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane DistillationLies Eykens0Klaus Rose1Marjorie Dubreuil2Kristien De Sitter3Chris Dotremont4Luc Pinoy5Bart Van der Bruggen6VITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumFraunhofer Institute for Silicate Research ISC, Neunerplatz 2, 97082 Würzburg, GermanyVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumDepartment of Chemical Engineering, Cluster Sustainable Chemical Process Technology, KU Leuven, Gebroeders Desmetstraat 1, B-9000 Ghent, BelgiumDepartment of Chemical Engineering, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, BelgiumMembrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a suitable structure for membrane distillation was modified using available hydrophobic coatings using ORMOCER® technology to obtain a hydrophobic membrane that can be applied in membrane distillation. The surface modification was performed using a selection of different components, concentrations, and application methods. The resulting membranes can have two hydrophobic surfaces or a hydrophobic and hydrophilic surface depending on the application method. An extensive characterization procedure confirmed the suitability of the coating technique and the obtained membranes for membrane distillation. The surface contact angle of water could be increased from 27° up to 110°, and fluxes comparable to membranes commonly used for membrane distillation were achieved under similar process conditions. A 100 h test demonstrated the stability of the coating and the importance of using sufficiently stable base membranes.http://www.mdpi.com/2076-3417/7/6/637hydrophobic coatingsdirect contact membrane distillation (DCMD)polyethersulfoneORMOCER®wetting
spellingShingle Lies Eykens
Klaus Rose
Marjorie Dubreuil
Kristien De Sitter
Chris Dotremont
Luc Pinoy
Bart Van der Bruggen
Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
Applied Sciences
hydrophobic coatings
direct contact membrane distillation (DCMD)
polyethersulfone
ORMOCER®
wetting
title Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
title_full Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
title_fullStr Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
title_full_unstemmed Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
title_short Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
title_sort functionalization of a hydrophilic commercial membrane using inorganic organic polymers coatings for membrane distillation
topic hydrophobic coatings
direct contact membrane distillation (DCMD)
polyethersulfone
ORMOCER®
wetting
url http://www.mdpi.com/2076-3417/7/6/637
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