Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation
Membrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a sui...
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MDPI AG
2017-06-01
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Series: | Applied Sciences |
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Online Access: | http://www.mdpi.com/2076-3417/7/6/637 |
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author | Lies Eykens Klaus Rose Marjorie Dubreuil Kristien De Sitter Chris Dotremont Luc Pinoy Bart Van der Bruggen |
author_facet | Lies Eykens Klaus Rose Marjorie Dubreuil Kristien De Sitter Chris Dotremont Luc Pinoy Bart Van der Bruggen |
author_sort | Lies Eykens |
collection | DOAJ |
description | Membrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a suitable structure for membrane distillation was modified using available hydrophobic coatings using ORMOCER® technology to obtain a hydrophobic membrane that can be applied in membrane distillation. The surface modification was performed using a selection of different components, concentrations, and application methods. The resulting membranes can have two hydrophobic surfaces or a hydrophobic and hydrophilic surface depending on the application method. An extensive characterization procedure confirmed the suitability of the coating technique and the obtained membranes for membrane distillation. The surface contact angle of water could be increased from 27° up to 110°, and fluxes comparable to membranes commonly used for membrane distillation were achieved under similar process conditions. A 100 h test demonstrated the stability of the coating and the importance of using sufficiently stable base membranes. |
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issn | 2076-3417 |
language | English |
last_indexed | 2024-04-11T23:53:53Z |
publishDate | 2017-06-01 |
publisher | MDPI AG |
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series | Applied Sciences |
spelling | doaj.art-3dceb45b6d9648a08e54468c988937ec2022-12-22T03:56:24ZengMDPI AGApplied Sciences2076-34172017-06-017663710.3390/app7060637app7060637Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane DistillationLies Eykens0Klaus Rose1Marjorie Dubreuil2Kristien De Sitter3Chris Dotremont4Luc Pinoy5Bart Van der Bruggen6VITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumFraunhofer Institute for Silicate Research ISC, Neunerplatz 2, 97082 Würzburg, GermanyVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumVITO-Flemish Institute for Technological Research, Boeretang 200, 2400 Mol, BelgiumDepartment of Chemical Engineering, Cluster Sustainable Chemical Process Technology, KU Leuven, Gebroeders Desmetstraat 1, B-9000 Ghent, BelgiumDepartment of Chemical Engineering, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, BelgiumMembrane distillation is a thermal separation technique using a microporous hydrophobic membrane. One of the concerns with respect to the industrialization of the technique is the development of novel membranes. In this paper, a commercially available hydrophilic polyethersulfone membrane with a suitable structure for membrane distillation was modified using available hydrophobic coatings using ORMOCER® technology to obtain a hydrophobic membrane that can be applied in membrane distillation. The surface modification was performed using a selection of different components, concentrations, and application methods. The resulting membranes can have two hydrophobic surfaces or a hydrophobic and hydrophilic surface depending on the application method. An extensive characterization procedure confirmed the suitability of the coating technique and the obtained membranes for membrane distillation. The surface contact angle of water could be increased from 27° up to 110°, and fluxes comparable to membranes commonly used for membrane distillation were achieved under similar process conditions. A 100 h test demonstrated the stability of the coating and the importance of using sufficiently stable base membranes.http://www.mdpi.com/2076-3417/7/6/637hydrophobic coatingsdirect contact membrane distillation (DCMD)polyethersulfoneORMOCER®wetting |
spellingShingle | Lies Eykens Klaus Rose Marjorie Dubreuil Kristien De Sitter Chris Dotremont Luc Pinoy Bart Van der Bruggen Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation Applied Sciences hydrophobic coatings direct contact membrane distillation (DCMD) polyethersulfone ORMOCER® wetting |
title | Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation |
title_full | Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation |
title_fullStr | Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation |
title_full_unstemmed | Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation |
title_short | Functionalization of a Hydrophilic Commercial Membrane Using Inorganic-Organic Polymers Coatings for Membrane Distillation |
title_sort | functionalization of a hydrophilic commercial membrane using inorganic organic polymers coatings for membrane distillation |
topic | hydrophobic coatings direct contact membrane distillation (DCMD) polyethersulfone ORMOCER® wetting |
url | http://www.mdpi.com/2076-3417/7/6/637 |
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