Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes
Bicyclo[1.1.0]butanes (BCBs) and [1.1.1]propellanes (tricyclo[1.1.1.01,3]pentanes, TCPs) are structurally unique compounds with different chemical properties. Strain-release driven reactions have emerged as an atom- and step-economic strategy for the organic synthesis. Using this strategy, a variety...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2024-03-01
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| Series: | Tetrahedron Chem |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666951X24000093 |
| _version_ | 1797247671431331840 |
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| author | Qian-Qian Hu Jie Chen Yang Yang Hui Yang Ling Zhou |
| author_facet | Qian-Qian Hu Jie Chen Yang Yang Hui Yang Ling Zhou |
| author_sort | Qian-Qian Hu |
| collection | DOAJ |
| description | Bicyclo[1.1.0]butanes (BCBs) and [1.1.1]propellanes (tricyclo[1.1.1.01,3]pentanes, TCPs) are structurally unique compounds with different chemical properties. Strain-release driven reactions have emerged as an atom- and step-economic strategy for the organic synthesis. Using this strategy, a variety of functional ring molecules have been efficiently synthesized, including various cyclobutane molecules, bicyclo[2.1.1]hexanes, bicyclo[1.1.1]pentanes, and others. More specifically, these strain release-driven reactions include aspects of nucleophilic addition, radical addition, electrophilic or transition metal catalysis. This review will discuss the recent developments in the strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes. |
| first_indexed | 2024-03-07T16:22:31Z |
| format | Article |
| id | doaj.art-3de1f1357c704062919d3c9cc7996937 |
| institution | Directory Open Access Journal |
| issn | 2666-951X |
| language | English |
| last_indexed | 2024-04-24T20:02:24Z |
| publishDate | 2024-03-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Tetrahedron Chem |
| spelling | doaj.art-3de1f1357c704062919d3c9cc79969372024-03-24T07:02:07ZengElsevierTetrahedron Chem2666-951X2024-03-019100070Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanesQian-Qian Hu0Jie Chen1Yang Yang2Hui Yang3Ling Zhou4Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, ChinaKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, ChinaKey Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, ChinaCollege of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an, 710054, China; Corresponding author.Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an, 710127, China; Corresponding author.Bicyclo[1.1.0]butanes (BCBs) and [1.1.1]propellanes (tricyclo[1.1.1.01,3]pentanes, TCPs) are structurally unique compounds with different chemical properties. Strain-release driven reactions have emerged as an atom- and step-economic strategy for the organic synthesis. Using this strategy, a variety of functional ring molecules have been efficiently synthesized, including various cyclobutane molecules, bicyclo[2.1.1]hexanes, bicyclo[1.1.1]pentanes, and others. More specifically, these strain release-driven reactions include aspects of nucleophilic addition, radical addition, electrophilic or transition metal catalysis. This review will discuss the recent developments in the strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes.http://www.sciencedirect.com/science/article/pii/S2666951X24000093Strain-release transformationBicyclo[1.1.0]butanes[1.1.1]Propellanes |
| spellingShingle | Qian-Qian Hu Jie Chen Yang Yang Hui Yang Ling Zhou Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes Tetrahedron Chem Strain-release transformation Bicyclo[1.1.0]butanes [1.1.1]Propellanes |
| title | Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes |
| title_full | Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes |
| title_fullStr | Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes |
| title_full_unstemmed | Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes |
| title_short | Strain-release transformations of bicyclo[1.1.0]butanes and [1.1.1]propellanes |
| title_sort | strain release transformations of bicyclo 1 1 0 butanes and 1 1 1 propellanes |
| topic | Strain-release transformation Bicyclo[1.1.0]butanes [1.1.1]Propellanes |
| url | http://www.sciencedirect.com/science/article/pii/S2666951X24000093 |
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