[μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C21H21P)(CO)9], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triangl...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809049940 |
| _version_ | 1819280153204752384 |
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| author | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Omar bin Shawkataly |
| collection | DOAJ |
| description | In the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C21H21P)(CO)9], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenylarsino groups. An intramolecular C—H...O hydrogen bond stabilizes the molecular structure. In the crystal packing, molecules are linked into chains down the b axis via intermolecular C—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T00:39:16Z |
| format | Article |
| id | doaj.art-3de3b22d8be4410db7130f26a2f0ed8a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:39:16Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3de3b22d8be4410db7130f26a2f0ed8a2022-12-21T17:24:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m36m3710.1107/S1600536809049940[μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0)Omar bin ShawkatalyImthyaz Ahmed KhanChin Sing YeapHoong-Kun FunIn the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C21H21P)(CO)9], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phenyl rings of the phosphine make dihedral angles of 86.89 (19), 82.1 (2) and 63.0 (2)° with each other. The dihedral angles between the two phenyl rings are 73.8 (2) and 82.2 (3)° for the two diphenylarsino groups. An intramolecular C—H...O hydrogen bond stabilizes the molecular structure. In the crystal packing, molecules are linked into chains down the b axis via intermolecular C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536809049940 |
| spellingShingle | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) Acta Crystallographica Section E |
| title | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
| title_full | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
| title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
| title_short | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)phosphine-3κP]-triangulo-triruthenium(0) |
| title_sort | amp 956 bis diphenylarsino methane 1 2 amp 954 2as as amp 8242 nonacarbonyl 1 amp 954 3c 2 amp 954 3c 3 amp 954 3c tris 4 methylphenyl phosphine 3 amp 954 p triangulo triruthenium 0 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809049940 |
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