(4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione
The title compound, C15H12N4O2, contains two independent molecules in the asymmetric unit. These differ in terms of dihedral angles that the phenyl and 2-pyridyl rings subtend with the central five-membered ring; 15.2 (2) and 2.9 (2)°, respectively, in one molecule, 8.9 (2) and 5.1 (2)°for the secon...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-06-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616009093 |
| _version_ | 1818313178484834304 |
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| author | Shaaban K. Mohamed Joel T. Mague Mehmet Akkurt Ahmed Khodairy Mustafa R. Albayati Eman A. Ahmed |
| author_facet | Shaaban K. Mohamed Joel T. Mague Mehmet Akkurt Ahmed Khodairy Mustafa R. Albayati Eman A. Ahmed |
| author_sort | Shaaban K. Mohamed |
| collection | DOAJ |
| description | The title compound, C15H12N4O2, contains two independent molecules in the asymmetric unit. These differ in terms of dihedral angles that the phenyl and 2-pyridyl rings subtend with the central five-membered ring; 15.2 (2) and 2.9 (2)°, respectively, in one molecule, 8.9 (2) and 5.1 (2)°for the second. In the crystal, the independent molecules each self-associate to form layers through N—H...O and C—H...O hydrogen bonding. The layers associate through π–π interactions between the phenyl rings and isolated carbon–carbon double bonds [shortest midpoint–centroid distance = 3.347 (4) Å]. The crystal studied was refined as a two-component twin. |
| first_indexed | 2024-12-13T08:29:37Z |
| format | Article |
| id | doaj.art-3defc377e69348ed8408dec63fd30963 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-13T08:29:37Z |
| publishDate | 2016-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-3defc377e69348ed8408dec63fd309632022-12-21T23:53:48ZengInternational Union of CrystallographyIUCrData2414-31462016-06-0116x16090910.1107/S2414314616009093tk4017(4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dioneShaaban K. Mohamed0Joel T. Mague1Mehmet Akkurt2Ahmed Khodairy3Mustafa R. Albayati4Eman A. Ahmed5Chemistry and Environmental Division, Manchester Metropolitan University, Manchester, M1 5GD, England, and, Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, EgyptDepartment of Chemistry, Tulane University, New Orleans, LA 70118, USADepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TurkeyChemistry Department, Faculty of Science, Sohagt University, Sohag, EgyptKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqKirkuk University, College of Science, Department of Chemistry, Kirkuk, IraqThe title compound, C15H12N4O2, contains two independent molecules in the asymmetric unit. These differ in terms of dihedral angles that the phenyl and 2-pyridyl rings subtend with the central five-membered ring; 15.2 (2) and 2.9 (2)°, respectively, in one molecule, 8.9 (2) and 5.1 (2)°for the second. In the crystal, the independent molecules each self-associate to form layers through N—H...O and C—H...O hydrogen bonding. The layers associate through π–π interactions between the phenyl rings and isolated carbon–carbon double bonds [shortest midpoint–centroid distance = 3.347 (4) Å]. The crystal studied was refined as a two-component twin.http://scripts.iucr.org/cgi-bin/paper?S2414314616009093crystal structurepyrazoldiones1,2,4-triazolesbenzyidene-acetohydrazide |
| spellingShingle | Shaaban K. Mohamed Joel T. Mague Mehmet Akkurt Ahmed Khodairy Mustafa R. Albayati Eman A. Ahmed (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione IUCrData crystal structure pyrazoldiones 1,2,4-triazoles benzyidene-acetohydrazide |
| title | (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione |
| title_full | (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione |
| title_fullStr | (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione |
| title_full_unstemmed | (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione |
| title_short | (4E)-1-Phenyl-4-{[(pyridin-2-yl)amino]methylidene}pyrazolidine-3,5-dione |
| title_sort | 4e 1 phenyl 4 pyridin 2 yl amino methylidene pyrazolidine 3 5 dione |
| topic | crystal structure pyrazoldiones 1,2,4-triazoles benzyidene-acetohydrazide |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616009093 |
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