Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
Abstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure wer...
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Format: | Article |
Language: | English |
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SpringerOpen
2019-02-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://link.springer.com/article/10.1186/s11671-019-2903-4 |
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author | Dawei He Fuyan Xiao Zhou Wang Aolin He Ruijiang Liu Guofan Jin |
author_facet | Dawei He Fuyan Xiao Zhou Wang Aolin He Ruijiang Liu Guofan Jin |
author_sort | Dawei He |
collection | DOAJ |
description | Abstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure were studied using a range of material characterization techniques. No covalent bonds were observed between molecules, and the self-assembled driving force was the only intermolecular interaction: Van der Waals’ force in the intra-layer and π–π interactions between layers. The arranged-rearranged structures provided a range of lithium ion shuttle channels, including the space between layers and diffusing through the nanosheets, which decrease the diffusion distance of lithium ions remarkably and reduce the irreversible capacity of the battery. |
first_indexed | 2024-03-12T19:31:23Z |
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institution | Directory Open Access Journal |
issn | 1931-7573 1556-276X |
language | English |
last_indexed | 2024-03-12T19:31:23Z |
publishDate | 2019-02-01 |
publisher | SpringerOpen |
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series | Nanoscale Research Letters |
spelling | doaj.art-3e40fe7aca014358b0f9a71281643e6a2023-08-02T04:27:12ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-02-011411810.1186/s11671-019-2903-4Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion StorageDawei He0Fuyan Xiao1Zhou Wang2Aolin He3Ruijiang Liu4Guofan Jin5Affiliated Kunshan Hospital, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversityCollege of Vanadium and Titanium, Panzhihua UniversityAffiliated Kunshan Hospital, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversityAbstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure were studied using a range of material characterization techniques. No covalent bonds were observed between molecules, and the self-assembled driving force was the only intermolecular interaction: Van der Waals’ force in the intra-layer and π–π interactions between layers. The arranged-rearranged structures provided a range of lithium ion shuttle channels, including the space between layers and diffusing through the nanosheets, which decrease the diffusion distance of lithium ions remarkably and reduce the irreversible capacity of the battery.http://link.springer.com/article/10.1186/s11671-019-2903-4HexabenzocoroneneDynamic hierarchical self-assembled-spacingRearrange |
spellingShingle | Dawei He Fuyan Xiao Zhou Wang Aolin He Ruijiang Liu Guofan Jin Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage Nanoscale Research Letters Hexabenzocoronene Dynamic hierarchical self-assemble d-spacing Rearrange |
title | Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage |
title_full | Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage |
title_fullStr | Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage |
title_full_unstemmed | Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage |
title_short | Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage |
title_sort | dynamic hierarchical self assemble small molecule structure hexabenzocoronene for the high performance anodes lithium ion storage |
topic | Hexabenzocoronene Dynamic hierarchical self-assemble d-spacing Rearrange |
url | http://link.springer.com/article/10.1186/s11671-019-2903-4 |
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