Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage

Abstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure wer...

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Main Authors: Dawei He, Fuyan Xiao, Zhou Wang, Aolin He, Ruijiang Liu, Guofan Jin
Format: Article
Language:English
Published: SpringerOpen 2019-02-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-019-2903-4
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author Dawei He
Fuyan Xiao
Zhou Wang
Aolin He
Ruijiang Liu
Guofan Jin
author_facet Dawei He
Fuyan Xiao
Zhou Wang
Aolin He
Ruijiang Liu
Guofan Jin
author_sort Dawei He
collection DOAJ
description Abstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure were studied using a range of material characterization techniques. No covalent bonds were observed between molecules, and the self-assembled driving force was the only intermolecular interaction: Van der Waals’ force in the intra-layer and π–π interactions between layers. The arranged-rearranged structures provided a range of lithium ion shuttle channels, including the space between layers and diffusing through the nanosheets, which decrease the diffusion distance of lithium ions remarkably and reduce the irreversible capacity of the battery.
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spelling doaj.art-3e40fe7aca014358b0f9a71281643e6a2023-08-02T04:27:12ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-02-011411810.1186/s11671-019-2903-4Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion StorageDawei He0Fuyan Xiao1Zhou Wang2Aolin He3Ruijiang Liu4Guofan Jin5Affiliated Kunshan Hospital, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversityCollege of Vanadium and Titanium, Panzhihua UniversityAffiliated Kunshan Hospital, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversitySchool of Pharmacy, Jiangsu UniversityAbstract This study examined the characteristics of small molecular structure nano-graphene in a dynamic hierarchical self-assembly and found that graphene is rearranged under its own pressure during dynamic aggregation and water ripples are formed by the d-spacing. The composition and structure were studied using a range of material characterization techniques. No covalent bonds were observed between molecules, and the self-assembled driving force was the only intermolecular interaction: Van der Waals’ force in the intra-layer and π–π interactions between layers. The arranged-rearranged structures provided a range of lithium ion shuttle channels, including the space between layers and diffusing through the nanosheets, which decrease the diffusion distance of lithium ions remarkably and reduce the irreversible capacity of the battery.http://link.springer.com/article/10.1186/s11671-019-2903-4HexabenzocoroneneDynamic hierarchical self-assembled-spacingRearrange
spellingShingle Dawei He
Fuyan Xiao
Zhou Wang
Aolin He
Ruijiang Liu
Guofan Jin
Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
Nanoscale Research Letters
Hexabenzocoronene
Dynamic hierarchical self-assemble
d-spacing
Rearrange
title Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
title_full Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
title_fullStr Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
title_full_unstemmed Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
title_short Dynamic Hierarchical Self-Assemble Small Molecule Structure Hexabenzocoronene for the High-Performance Anodes Lithium Ion Storage
title_sort dynamic hierarchical self assemble small molecule structure hexabenzocoronene for the high performance anodes lithium ion storage
topic Hexabenzocoronene
Dynamic hierarchical self-assemble
d-spacing
Rearrange
url http://link.springer.com/article/10.1186/s11671-019-2903-4
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