Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research

Cementitious materials have complex compositions and structures. Characterization of the hydration processes, and compositions and structure of productions of cementitious materials is challenging. One-dimensional solid-state nuclear magnetic resonance (NMR) is used to analyze the hydration degree o...

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Main Authors: WANG Ke, ZHANG Ying-hua, LI Yu-qing, ZOU Ding-hua
Format: Article
Language:zho
Published: Science Press 2020-03-01
Series:Chinese Journal of Magnetic Resonance
Subjects:
Online Access:http://121.43.60.238/bpxzz/EN/10.11938/cjmr20192747
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author WANG Ke
ZHANG Ying-hua
LI Yu-qing
ZOU Ding-hua
author_facet WANG Ke
ZHANG Ying-hua
LI Yu-qing
ZOU Ding-hua
author_sort WANG Ke
collection DOAJ
description Cementitious materials have complex compositions and structures. Characterization of the hydration processes, and compositions and structure of productions of cementitious materials is challenging. One-dimensional solid-state nuclear magnetic resonance (NMR) is used to analyze the hydration degree of the binders (i.e., cement and mineral admixtures), as well as the species and structure of the hydration products (especially the non-crystal components), both qualitatively or quantitatively. Thereby, the effects of binder components, additives, and environment on the hydration process can be investigated. Two-dimensional NMR spectroscopy can provide further information on the connections between the same or different nuclei, confirming the presence of doping and substitution in the hydration products, as well as dispersion of organic additives in the matrix. It is concluded that solid-state NMR technology can be used to obtain information that rarely provided by other methods, and may advance the research on hydration process and microstructure of the cementitious materials.
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spelling doaj.art-3e4f7a48040e41e290316681b4a91b4d2022-12-21T22:20:46ZzhoScience PressChinese Journal of Magnetic Resonance1000-45561000-45562020-03-013701405110.11938/cjmr20192747Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials ResearchWANG Ke0ZHANG Ying-hua1LI Yu-qing2ZOU Ding-hua3School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, ChinaSchool of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, ChinaSchool of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, ChinaSchool of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454000, ChinaCementitious materials have complex compositions and structures. Characterization of the hydration processes, and compositions and structure of productions of cementitious materials is challenging. One-dimensional solid-state nuclear magnetic resonance (NMR) is used to analyze the hydration degree of the binders (i.e., cement and mineral admixtures), as well as the species and structure of the hydration products (especially the non-crystal components), both qualitatively or quantitatively. Thereby, the effects of binder components, additives, and environment on the hydration process can be investigated. Two-dimensional NMR spectroscopy can provide further information on the connections between the same or different nuclei, confirming the presence of doping and substitution in the hydration products, as well as dispersion of organic additives in the matrix. It is concluded that solid-state NMR technology can be used to obtain information that rarely provided by other methods, and may advance the research on hydration process and microstructure of the cementitious materials.http://121.43.60.238/bpxzz/EN/10.11938/cjmr20192747nuclear magnetic resonancecementitious materialschemical shifthydrationc-s-h gel
spellingShingle WANG Ke
ZHANG Ying-hua
LI Yu-qing
ZOU Ding-hua
Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
Chinese Journal of Magnetic Resonance
nuclear magnetic resonance
cementitious materials
chemical shift
hydration
c-s-h gel
title Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
title_full Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
title_fullStr Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
title_full_unstemmed Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
title_short Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Cementitious Materials Research
title_sort applications of solid state nuclear magnetic resonance spectroscopy in cementitious materials research
topic nuclear magnetic resonance
cementitious materials
chemical shift
hydration
c-s-h gel
url http://121.43.60.238/bpxzz/EN/10.11938/cjmr20192747
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AT zhangyinghua applicationsofsolidstatenuclearmagneticresonancespectroscopyincementitiousmaterialsresearch
AT liyuqing applicationsofsolidstatenuclearmagneticresonancespectroscopyincementitiousmaterialsresearch
AT zoudinghua applicationsofsolidstatenuclearmagneticresonancespectroscopyincementitiousmaterialsresearch