Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries
Its high nominal voltage, thermal stability, and low toxicity render LiMn2O4 a highly promising cathode material for lithium ion batteries, but capacity fading due to unwanted side reactions during cycling remains an issue. Here, the authors show that carbon-coating a LiMn2O4 cathode reduces side re...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2022-04-01
|
Series: | Communications Chemistry |
Online Access: | https://doi.org/10.1038/s42004-022-00670-y |
_version_ | 1818522645742747648 |
---|---|
author | Chanikarn Tomon Sangchai Sarawutanukul Nutthaphon Phattharasupakun Salatan Duangdangchote Praeploy Chomkhuntod Nattanon Joraleechanchai Panyawee Bunyanidhi Montree Sawangphruk |
author_facet | Chanikarn Tomon Sangchai Sarawutanukul Nutthaphon Phattharasupakun Salatan Duangdangchote Praeploy Chomkhuntod Nattanon Joraleechanchai Panyawee Bunyanidhi Montree Sawangphruk |
author_sort | Chanikarn Tomon |
collection | DOAJ |
description | Its high nominal voltage, thermal stability, and low toxicity render LiMn2O4 a highly promising cathode material for lithium ion batteries, but capacity fading due to unwanted side reactions during cycling remains an issue. Here, the authors show that carbon-coating a LiMn2O4 cathode reduces side reactions such as manganese dissolution and manganese oxide formation, thereby improving battery cycling stability. |
first_indexed | 2024-12-11T05:36:02Z |
format | Article |
id | doaj.art-3e5525a82ee843de99d5ed8920738296 |
institution | Directory Open Access Journal |
issn | 2399-3669 |
language | English |
last_indexed | 2024-12-11T05:36:02Z |
publishDate | 2022-04-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Communications Chemistry |
spelling | doaj.art-3e5525a82ee843de99d5ed89207382962022-12-22T01:19:16ZengNature PortfolioCommunications Chemistry2399-36692022-04-015111210.1038/s42004-022-00670-yCore-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteriesChanikarn Tomon0Sangchai Sarawutanukul1Nutthaphon Phattharasupakun2Salatan Duangdangchote3Praeploy Chomkhuntod4Nattanon Joraleechanchai5Panyawee BunyanidhiMontree Sawangphruk6Center of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyCenter of Excellence for Energy Storage Technology (CEST), Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and TechnologyIts high nominal voltage, thermal stability, and low toxicity render LiMn2O4 a highly promising cathode material for lithium ion batteries, but capacity fading due to unwanted side reactions during cycling remains an issue. Here, the authors show that carbon-coating a LiMn2O4 cathode reduces side reactions such as manganese dissolution and manganese oxide formation, thereby improving battery cycling stability.https://doi.org/10.1038/s42004-022-00670-y |
spellingShingle | Chanikarn Tomon Sangchai Sarawutanukul Nutthaphon Phattharasupakun Salatan Duangdangchote Praeploy Chomkhuntod Nattanon Joraleechanchai Panyawee Bunyanidhi Montree Sawangphruk Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries Communications Chemistry |
title | Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries |
title_full | Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries |
title_fullStr | Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries |
title_full_unstemmed | Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries |
title_short | Core-shell structure of LiMn2O4 cathode material reduces phase transition and Mn dissolution in Li-ion batteries |
title_sort | core shell structure of limn2o4 cathode material reduces phase transition and mn dissolution in li ion batteries |
url | https://doi.org/10.1038/s42004-022-00670-y |
work_keys_str_mv | AT chanikarntomon coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT sangchaisarawutanukul coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT nutthaphonphattharasupakun coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT salatanduangdangchote coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT praeploychomkhuntod coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT nattanonjoraleechanchai coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT panyaweebunyanidhi coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries AT montreesawangphruk coreshellstructureoflimn2o4cathodematerialreducesphasetransitionandmndissolutioninliionbatteries |