A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties
A solvent- and halogen-free synthesis of high purity triflate ionic liquids via direct alkylation of organic bases (amines, phosphines or heterocyclic compounds) with methyl and ethyl trifluoromethanesulfonate (methyl and ethyl triflate) has been developed. Cheap and non-toxic dimethyl and diethyl c...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-05-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/17/5/5319 |
| _version_ | 1819230214772752384 |
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| author | Peter Sartori Andryi Kucheryna Helge Willner Nikolai V. Ignat’ev Peter Barthen |
| author_facet | Peter Sartori Andryi Kucheryna Helge Willner Nikolai V. Ignat’ev Peter Barthen |
| author_sort | Peter Sartori |
| collection | DOAJ |
| description | A solvent- and halogen-free synthesis of high purity triflate ionic liquids via direct alkylation of organic bases (amines, phosphines or heterocyclic compounds) with methyl and ethyl trifluoromethanesulfonate (methyl and ethyl triflate) has been developed. Cheap and non-toxic dimethyl and diethyl carbonate serve as source for the methyl and ethyl groups in the preparation of methyl and ethyl triflate by this invented process. The properties of ionic liquids containing the triflate anion are determined and discussed. |
| first_indexed | 2024-12-23T11:25:31Z |
| format | Article |
| id | doaj.art-3e88629f493641278e0e77b976a5abfa |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-23T11:25:31Z |
| publishDate | 2012-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-3e88629f493641278e0e77b976a5abfa2022-12-21T17:48:57ZengMDPI AGMolecules1420-30492012-05-011755319533810.3390/molecules17055319A Convenient Synthesis of Triflate Anion Ionic Liquids and Their PropertiesPeter SartoriAndryi KucherynaHelge WillnerNikolai V. Ignat’evPeter BarthenA solvent- and halogen-free synthesis of high purity triflate ionic liquids via direct alkylation of organic bases (amines, phosphines or heterocyclic compounds) with methyl and ethyl trifluoromethanesulfonate (methyl and ethyl triflate) has been developed. Cheap and non-toxic dimethyl and diethyl carbonate serve as source for the methyl and ethyl groups in the preparation of methyl and ethyl triflate by this invented process. The properties of ionic liquids containing the triflate anion are determined and discussed.http://www.mdpi.com/1420-3049/17/5/5319methyl triflateethyl triflateionic liquidsviscosity |
| spellingShingle | Peter Sartori Andryi Kucheryna Helge Willner Nikolai V. Ignat’ev Peter Barthen A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties Molecules methyl triflate ethyl triflate ionic liquids viscosity |
| title | A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties |
| title_full | A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties |
| title_fullStr | A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties |
| title_full_unstemmed | A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties |
| title_short | A Convenient Synthesis of Triflate Anion Ionic Liquids and Their Properties |
| title_sort | convenient synthesis of triflate anion ionic liquids and their properties |
| topic | methyl triflate ethyl triflate ionic liquids viscosity |
| url | http://www.mdpi.com/1420-3049/17/5/5319 |
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