Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives

Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N-arylaminocyclopropane with alkyne derivatives

Dirhodium(II) complex-catalyzed [3 + 2] reactions between N-arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. trans-Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddit...

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Bibliographic Details
Main Authors: Wentong Liu, Yi Kuang, Zhifan Wang, Jin Zhu, Yuanhua Wang
Format: Article
Language:English
Published: Beilstein-Institut 2019-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
[3 + 2]
alkyne
cycloaddition
cyclopropanes
dirhodium catalysis
N-arylaminocyclopropanes
Online Access:https://doi.org/10.3762/bjoc.15.48

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