Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air

Hydrogen is a valuable fuel for the next energy scenario. Unfortunately, hydrogen is highly flammable at concentrations higher than 4% in air. This aspect makes the monitoring of H2 leaks an essential issue for safety reasons, especially in the transportation field. In this paper, nanocomposites bas...

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Main Authors: Stefano Trocino, Andrea Donato, Mariangela Latino, Nicola Donato, Salvatore Gianluca Leonardi, Giovanni Neri
Format: Article
Language:English
Published: MDPI AG 2012-09-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/12/9/12361
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author Stefano Trocino
Andrea Donato
Mariangela Latino
Nicola Donato
Salvatore Gianluca Leonardi
Giovanni Neri
author_facet Stefano Trocino
Andrea Donato
Mariangela Latino
Nicola Donato
Salvatore Gianluca Leonardi
Giovanni Neri
author_sort Stefano Trocino
collection DOAJ
description Hydrogen is a valuable fuel for the next energy scenario. Unfortunately, hydrogen is highly flammable at concentrations higher than 4% in air. This aspect makes the monitoring of H2 leaks an essential issue for safety reasons, especially in the transportation field. In this paper, nanocomposites based on Pt-doped TiO2/multiwalled carbon nanotubes (MWCNTs) have been introduced as sensitive materials for H2 at low temperatures. Pt-TiO2/MWNTs nanocomposites with different composition have been prepared by a simple wet chemical procedure and their morphological, microstructural and electrical properties were investigated. Resistive thick-film devices have been fabricated printing the hybrid nanocomposites on alumina substrates provided with Pt interdigitated electrodes. Electrical tests in air have shown that embedding MWCNTs in the TiO2 matrix modify markedly the electrical conductivity, providing a means to decrease the resistance of the sensing layer. Pt acts as a catalytic additive. Pt-TiO2/MWNTs-based sensors were found to be sensitive to hydrogen at concentrations between 0.5 and 3% in air, satisfying the requisites for practical applications in hydrogen leak detection devices.
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spelling doaj.art-3e97b5de34764dd68a3300a62a80663d2022-12-22T04:21:14ZengMDPI AGSensors1424-82202012-09-01129123611237310.3390/s120912361Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in AirStefano TrocinoAndrea DonatoMariangela LatinoNicola DonatoSalvatore Gianluca LeonardiGiovanni NeriHydrogen is a valuable fuel for the next energy scenario. Unfortunately, hydrogen is highly flammable at concentrations higher than 4% in air. This aspect makes the monitoring of H2 leaks an essential issue for safety reasons, especially in the transportation field. In this paper, nanocomposites based on Pt-doped TiO2/multiwalled carbon nanotubes (MWCNTs) have been introduced as sensitive materials for H2 at low temperatures. Pt-TiO2/MWNTs nanocomposites with different composition have been prepared by a simple wet chemical procedure and their morphological, microstructural and electrical properties were investigated. Resistive thick-film devices have been fabricated printing the hybrid nanocomposites on alumina substrates provided with Pt interdigitated electrodes. Electrical tests in air have shown that embedding MWCNTs in the TiO2 matrix modify markedly the electrical conductivity, providing a means to decrease the resistance of the sensing layer. Pt acts as a catalytic additive. Pt-TiO2/MWNTs-based sensors were found to be sensitive to hydrogen at concentrations between 0.5 and 3% in air, satisfying the requisites for practical applications in hydrogen leak detection devices.http://www.mdpi.com/1424-8220/12/9/12361hydrogen sensorTiO2MWCNTshybrid nanocomposites
spellingShingle Stefano Trocino
Andrea Donato
Mariangela Latino
Nicola Donato
Salvatore Gianluca Leonardi
Giovanni Neri
Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
Sensors
hydrogen sensor
TiO2
MWCNTs
hybrid nanocomposites
title Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
title_full Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
title_fullStr Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
title_full_unstemmed Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
title_short Pt-TiO2/MWCNTs Hybrid Composites for Monitoring Low Hydrogen Concentrations in Air
title_sort pt tio2 mwcnts hybrid composites for monitoring low hydrogen concentrations in air
topic hydrogen sensor
TiO2
MWCNTs
hybrid nanocomposites
url http://www.mdpi.com/1424-8220/12/9/12361
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