Effect of Silane Coupling Agents on Cotton Fibre Finishing
Five different silane coupling agents such as vinyltrimethoxysilane (VTMS), vinyltriethoxysilane (VTES), trimethoxysilylpropylmethacrylate (TSPM), glycidoxypropyltriethoxysilane (GPTES) and aminopropyltriethoxysilane (APTES) were used for the surface finishing of cotton fiber by condensation polymer...
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Format: | Article |
Language: | English |
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Taylor & Francis Group
2022-12-01
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Series: | Journal of Natural Fibers |
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Online Access: | http://dx.doi.org/10.1080/15440478.2021.1875382 |
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author | Md. Ibrahim H. Mondal Md. Khademul Islam Firoz Ahmed |
author_facet | Md. Ibrahim H. Mondal Md. Khademul Islam Firoz Ahmed |
author_sort | Md. Ibrahim H. Mondal |
collection | DOAJ |
description | Five different silane coupling agents such as vinyltrimethoxysilane (VTMS), vinyltriethoxysilane (VTES), trimethoxysilylpropylmethacrylate (TSPM), glycidoxypropyltriethoxysilane (GPTES) and aminopropyltriethoxysilane (APTES) were used for the surface finishing of cotton fiber by condensation polymerization in ethanol/water medium. The finished cotton fiber showed improved textile properties like tensile strength, wear comfortness, moisture absorption and wrinkle recovery, but decreased swelling in aqueous solution. The finished cotton fibers were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Energy Dispersive X-ray (EDX), thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG). Attachment of silane coupling agents was confirmed and the finished cotton fiber showed increased thermal stability than the unfinished cotton. The finished cotton fiber showed higher reactive dye exhaustion due to silane coupling agent imparts new reactive sites for dye molecule on cotton fiber. The finished cotton fiber showed excellent fastness properties like washing, sunlight and chemical fastness properties. Improved textile properties of the silane finished cotton fiber with higher flexibility due to the presence of Si-O bond between the silane coupling agents and the cotton fiber, causes increased wear comfortness. Possible applications include use of the finished fibers as textile materials and garments. |
first_indexed | 2024-03-11T23:24:36Z |
format | Article |
id | doaj.art-3ebb077c71b9489ab7d9e034f9085b77 |
institution | Directory Open Access Journal |
issn | 1544-0478 1544-046X |
language | English |
last_indexed | 2024-03-11T23:24:36Z |
publishDate | 2022-12-01 |
publisher | Taylor & Francis Group |
record_format | Article |
series | Journal of Natural Fibers |
spelling | doaj.art-3ebb077c71b9489ab7d9e034f9085b772023-09-20T13:04:27ZengTaylor & Francis GroupJournal of Natural Fibers1544-04781544-046X2022-12-0119135451546410.1080/15440478.2021.18753821875382Effect of Silane Coupling Agents on Cotton Fibre FinishingMd. Ibrahim H. Mondal0Md. Khademul Islam1Firoz Ahmed2Polymer and Textile Research Laboratory, Rajshahi UniversityPolymer and Textile Research Laboratory, Rajshahi UniversityPolymer and Textile Research Laboratory, Rajshahi UniversityFive different silane coupling agents such as vinyltrimethoxysilane (VTMS), vinyltriethoxysilane (VTES), trimethoxysilylpropylmethacrylate (TSPM), glycidoxypropyltriethoxysilane (GPTES) and aminopropyltriethoxysilane (APTES) were used for the surface finishing of cotton fiber by condensation polymerization in ethanol/water medium. The finished cotton fiber showed improved textile properties like tensile strength, wear comfortness, moisture absorption and wrinkle recovery, but decreased swelling in aqueous solution. The finished cotton fibers were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD) and Energy Dispersive X-ray (EDX), thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG). Attachment of silane coupling agents was confirmed and the finished cotton fiber showed increased thermal stability than the unfinished cotton. The finished cotton fiber showed higher reactive dye exhaustion due to silane coupling agent imparts new reactive sites for dye molecule on cotton fiber. The finished cotton fiber showed excellent fastness properties like washing, sunlight and chemical fastness properties. Improved textile properties of the silane finished cotton fiber with higher flexibility due to the presence of Si-O bond between the silane coupling agents and the cotton fiber, causes increased wear comfortness. Possible applications include use of the finished fibers as textile materials and garments.http://dx.doi.org/10.1080/15440478.2021.1875382cotton fibersilane coupling agentstextilesfinishingfibersswelling behavior |
spellingShingle | Md. Ibrahim H. Mondal Md. Khademul Islam Firoz Ahmed Effect of Silane Coupling Agents on Cotton Fibre Finishing Journal of Natural Fibers cotton fiber silane coupling agents textiles finishing fibers swelling behavior |
title | Effect of Silane Coupling Agents on Cotton Fibre Finishing |
title_full | Effect of Silane Coupling Agents on Cotton Fibre Finishing |
title_fullStr | Effect of Silane Coupling Agents on Cotton Fibre Finishing |
title_full_unstemmed | Effect of Silane Coupling Agents on Cotton Fibre Finishing |
title_short | Effect of Silane Coupling Agents on Cotton Fibre Finishing |
title_sort | effect of silane coupling agents on cotton fibre finishing |
topic | cotton fiber silane coupling agents textiles finishing fibers swelling behavior |
url | http://dx.doi.org/10.1080/15440478.2021.1875382 |
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