Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste
Pharmaceutical pollution has pervaded many water resources all over the globe. The propagation of this health threat drew the researchers’ concern in seeking an efficient solution. This study introduced toilet paper waste as a precursor for carbon nanoparticles (CRNPs). The TEM results showed a part...
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MDPI AG
2022-10-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/12/20/3617 |
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| author | Rasmiah S. Almufarij Babiker Y. Abdulkhair Mutaz Salih Nujud M. Alhamdan |
| author_facet | Rasmiah S. Almufarij Babiker Y. Abdulkhair Mutaz Salih Nujud M. Alhamdan |
| author_sort | Rasmiah S. Almufarij |
| collection | DOAJ |
| description | Pharmaceutical pollution has pervaded many water resources all over the globe. The propagation of this health threat drew the researchers’ concern in seeking an efficient solution. This study introduced toilet paper waste as a precursor for carbon nanoparticles (CRNPs). The TEM results showed a particle size range of 30.2 nm to 48.1 nm, the BET surface area was 283 m<sup>2</sup> g<sup>−1</sup>, and the XRD pattern indicated cubical-graphite crystals. The synthesized CRNPs were tested for removing tigecycline (TGCN), chlortetracycline (CTCN), oxytetracycline (OTCN), and doxycycline (DXCN) via the batch process. The adsorption equilibrium time for TGCN, DXCN, CTCN, and OTCN was 60 min, and the concentration influence revealed an adsorption capacity of 172.5, 200.1, 202.4, and 200.0 mg g<sup>−1,</sup> respectively. The sorption of the four drugs followed the PSFO, and the LFDM models indicated their high sorption affinity to the CRNPs. The adsorption of the four drugs fitted the multilayer FIM that supported the high-affinity claim. The removals of the four drugs were exothermic and spontaneous physisorption. The fabricated CRNPs possessed an excellent remediation efficiency for contaminated SW and GW; therefore, CRNPs are suggested for water remediation as low-cost sorbent. |
| first_indexed | 2024-03-09T19:40:20Z |
| format | Article |
| id | doaj.art-3ebc7be912bf419a86852788c91fd103 |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-09T19:40:20Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-3ebc7be912bf419a86852788c91fd1032023-11-24T01:40:21ZengMDPI AGNanomaterials2079-49912022-10-011220361710.3390/nano12203617Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue WasteRasmiah S. Almufarij0Babiker Y. Abdulkhair1Mutaz Salih2Nujud M. Alhamdan3Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi ArabiaChemistry Department, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 90905, Riyadh 11623, Saudi ArabiaDepartment of Chemistry, College of Science and Humanities-Hurrymilla, Imam Mohammad Ibn Saud Islamic University (IMSIU), P.O. Box 5701, Riyadh 11432, Saudi ArabiaDepartment of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi ArabiaPharmaceutical pollution has pervaded many water resources all over the globe. The propagation of this health threat drew the researchers’ concern in seeking an efficient solution. This study introduced toilet paper waste as a precursor for carbon nanoparticles (CRNPs). The TEM results showed a particle size range of 30.2 nm to 48.1 nm, the BET surface area was 283 m<sup>2</sup> g<sup>−1</sup>, and the XRD pattern indicated cubical-graphite crystals. The synthesized CRNPs were tested for removing tigecycline (TGCN), chlortetracycline (CTCN), oxytetracycline (OTCN), and doxycycline (DXCN) via the batch process. The adsorption equilibrium time for TGCN, DXCN, CTCN, and OTCN was 60 min, and the concentration influence revealed an adsorption capacity of 172.5, 200.1, 202.4, and 200.0 mg g<sup>−1,</sup> respectively. The sorption of the four drugs followed the PSFO, and the LFDM models indicated their high sorption affinity to the CRNPs. The adsorption of the four drugs fitted the multilayer FIM that supported the high-affinity claim. The removals of the four drugs were exothermic and spontaneous physisorption. The fabricated CRNPs possessed an excellent remediation efficiency for contaminated SW and GW; therefore, CRNPs are suggested for water remediation as low-cost sorbent.https://www.mdpi.com/2079-4991/12/20/3617carbon nanoparticlestoilet papertigecyclinechlortetracyclineoxytetracyclinedoxycycline |
| spellingShingle | Rasmiah S. Almufarij Babiker Y. Abdulkhair Mutaz Salih Nujud M. Alhamdan Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste Nanomaterials carbon nanoparticles toilet paper tigecycline chlortetracycline oxytetracycline doxycycline |
| title | Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste |
| title_full | Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste |
| title_fullStr | Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste |
| title_full_unstemmed | Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste |
| title_short | Sweep-Out of Tigecycline, Chlortetracycline, Oxytetracycline, and Doxycycline from Water by Carbon Nanoparticles Derived from Tissue Waste |
| title_sort | sweep out of tigecycline chlortetracycline oxytetracycline and doxycycline from water by carbon nanoparticles derived from tissue waste |
| topic | carbon nanoparticles toilet paper tigecycline chlortetracycline oxytetracycline doxycycline |
| url | https://www.mdpi.com/2079-4991/12/20/3617 |
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