Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4
Single crystals of SrFe1.40V0.60O4, strontium tetraoxidodi[ferrate(III)/vanadate(III)], have been obtained as a side product in the course of sinter experiments aimed at the synthesis of double perovskites in the system SrO–Fe2O3–V2O5. The crystal structure can be characterized by layers of six-memb...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S205698902000496X |
| _version_ | 1798018652083060736 |
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| author | Thomas Gstir Volker Kahlenberg Hannes Krüger Simon Penner |
| author_facet | Thomas Gstir Volker Kahlenberg Hannes Krüger Simon Penner |
| author_sort | Thomas Gstir |
| collection | DOAJ |
| description | Single crystals of SrFe1.40V0.60O4, strontium tetraoxidodi[ferrate(III)/vanadate(III)], have been obtained as a side product in the course of sinter experiments aimed at the synthesis of double perovskites in the system SrO–Fe2O3–V2O5. The crystal structure can be characterized by layers of six-membered rings of TO4-tetrahedra (T: FeIII, VIII) perpendicular to [100]. Stacking of the layers along [100] results in a three-dimensional framework enclosing tunnel-like cavities in which SrII cations are incorporated for charge compensation. The sequence of directedness of up (U) and down (D) pointing vertices of neighboring tetrahedra in a single six-membered ring is UUUDDD. The topology of the tetrahedral framework belongs to the zeolite-type ABW. |
| first_indexed | 2024-04-11T16:27:55Z |
| format | Article |
| id | doaj.art-3efa72c1237f4188811fe34f8d55d0eb |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-11T16:27:55Z |
| publishDate | 2020-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-3efa72c1237f4188811fe34f8d55d0eb2022-12-22T04:14:07ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-05-0176566466710.1107/S205698902000496Xwm5552Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4Thomas Gstir0Volker Kahlenberg1Hannes Krüger2Simon Penner3University of Innsbruck, Institute of Mineralogy & Petrography, Innrain 52, A-6020 Innsbruck, AustriaUniversity of Innsbruck, Institute of Mineralogy & Petrography, Innrain 52, A-6020 Innsbruck, AustriaUniversity of Innsbruck, Institute of Mineralogy & Petrography, Innrain 52, A-6020 Innsbruck, AustriaUniversity of Innsbruck, Department of Physical Chemistry, Innrain 52c, A-6020 Innsbruck, AustriaSingle crystals of SrFe1.40V0.60O4, strontium tetraoxidodi[ferrate(III)/vanadate(III)], have been obtained as a side product in the course of sinter experiments aimed at the synthesis of double perovskites in the system SrO–Fe2O3–V2O5. The crystal structure can be characterized by layers of six-membered rings of TO4-tetrahedra (T: FeIII, VIII) perpendicular to [100]. Stacking of the layers along [100] results in a three-dimensional framework enclosing tunnel-like cavities in which SrII cations are incorporated for charge compensation. The sequence of directedness of up (U) and down (D) pointing vertices of neighboring tetrahedra in a single six-membered ring is UUUDDD. The topology of the tetrahedral framework belongs to the zeolite-type ABW.http://scripts.iucr.org/cgi-bin/paper?S205698902000496Xcrystal structurecation substitutionsolid solutiontopologyzeoliteabw |
| spellingShingle | Thomas Gstir Volker Kahlenberg Hannes Krüger Simon Penner Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 Acta Crystallographica Section E: Crystallographic Communications crystal structure cation substitution solid solution topology zeolite abw |
| title | Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 |
| title_full | Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 |
| title_fullStr | Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 |
| title_full_unstemmed | Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 |
| title_short | Synthesis and crystal structure of ABW-type SrFe1.40V0.60O4 |
| title_sort | synthesis and crystal structure of abw type srfe1 40v0 60o4 |
| topic | crystal structure cation substitution solid solution topology zeolite abw |
| url | http://scripts.iucr.org/cgi-bin/paper?S205698902000496X |
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