Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites

In this study, we have investigated the electrochemical corrosion behavior of boron carbide (B<sub>4</sub>C) ceramic-reinforced Al-Mg-Si matrix composites in various aqueous environments (NaOH, NaCl, HCl, and H<sub>2</sub>SO<sub>4</sub>). The samples were produced...

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Main Authors: Neeraj Kumar, Ashutosh Sharma, Manoranjan Kumar Manoj
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/23/8531
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author Neeraj Kumar
Ashutosh Sharma
Manoranjan Kumar Manoj
author_facet Neeraj Kumar
Ashutosh Sharma
Manoranjan Kumar Manoj
author_sort Neeraj Kumar
collection DOAJ
description In this study, we have investigated the electrochemical corrosion behavior of boron carbide (B<sub>4</sub>C) ceramic-reinforced Al-Mg-Si matrix composites in various aqueous environments (NaOH, NaCl, HCl, and H<sub>2</sub>SO<sub>4</sub>). The samples were produced by the powder metallurgy (P/M) route and the corrosion investigations were conducted by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) methods. The morphology of the as-prepared and corroded samples was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) studies. The investigations revealed that the corrosion resistance of Al-Mg-Si composites is highest in NaCl medium due to a less negative corrosion potential, higher charge transfer (R<sub>ct</sub>) resistance, and lower double-layer capacitance (C<sub>dl</sub>) as compared to other media. The SEM morphology suggests that B<sub>4</sub>C ceramics enhance corrosion resistance by forming a protective barrier layer of OH- and Cl- deposits in the composite and unreinforced alloy, respectively.
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spelling doaj.art-3f0574a6a727495fba7f21780629b7a62023-11-24T11:29:52ZengMDPI AGMaterials1996-19442022-11-011523853110.3390/ma15238531Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix CompositesNeeraj Kumar0Ashutosh Sharma1Manoranjan Kumar Manoj2Metallurgical and Materials Engineering, National Institute of Technology (NIT), Raipur 492010, IndiaDepartment of Materials Science and Engineering, Ajou University, Suwon 16499, Republic of KoreaMetallurgical and Materials Engineering, National Institute of Technology (NIT), Raipur 492010, IndiaIn this study, we have investigated the electrochemical corrosion behavior of boron carbide (B<sub>4</sub>C) ceramic-reinforced Al-Mg-Si matrix composites in various aqueous environments (NaOH, NaCl, HCl, and H<sub>2</sub>SO<sub>4</sub>). The samples were produced by the powder metallurgy (P/M) route and the corrosion investigations were conducted by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) methods. The morphology of the as-prepared and corroded samples was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) studies. The investigations revealed that the corrosion resistance of Al-Mg-Si composites is highest in NaCl medium due to a less negative corrosion potential, higher charge transfer (R<sub>ct</sub>) resistance, and lower double-layer capacitance (C<sub>dl</sub>) as compared to other media. The SEM morphology suggests that B<sub>4</sub>C ceramics enhance corrosion resistance by forming a protective barrier layer of OH- and Cl- deposits in the composite and unreinforced alloy, respectively.https://www.mdpi.com/1996-1944/15/23/8531corrosionpowder metallurgymetal matrix composite (MMC)ceramicsaluminum alloys
spellingShingle Neeraj Kumar
Ashutosh Sharma
Manoranjan Kumar Manoj
Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
Materials
corrosion
powder metallurgy
metal matrix composite (MMC)
ceramics
aluminum alloys
title Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
title_full Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
title_fullStr Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
title_full_unstemmed Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
title_short Influence of Different Aqueous Media on the Corrosion Behavior of B<sub>4</sub>C-Modified Lightweight Al-Mg-Si Matrix Composites
title_sort influence of different aqueous media on the corrosion behavior of b sub 4 sub c modified lightweight al mg si matrix composites
topic corrosion
powder metallurgy
metal matrix composite (MMC)
ceramics
aluminum alloys
url https://www.mdpi.com/1996-1944/15/23/8531
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AT ashutoshsharma influenceofdifferentaqueousmediaonthecorrosionbehaviorofbsub4subcmodifiedlightweightalmgsimatrixcomposites
AT manoranjankumarmanoj influenceofdifferentaqueousmediaonthecorrosionbehaviorofbsub4subcmodifiedlightweightalmgsimatrixcomposites