(La0.2Dy0.2Nd0.2Sm0.2Eu0.2)2GdTaO7: a promising candidate oxides for high-temperature coating applications

In the paper, the (La0.2Dy0.2Nd0.2Sm0.2Eu0.2)2GdTaO7 oxide was prepared employing sol–gel and solid-reaction method. Its crystal-structure, microstructure, element-distribution, mechanical and thermophysical properties are investigated. The analytical conclusions reveal that this high-entropy oxide...

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Bibliographic Details
Main Authors: Haoming Zhang, Hongsong Zhang, Shuaixia Liu, Xianping Zhang, Xiaoge Chen, Hong Wang, Yinghui Wang, Huanlin Duan, Yongfei Xue
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423015053
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Summary:In the paper, the (La0.2Dy0.2Nd0.2Sm0.2Eu0.2)2GdTaO7 oxide was prepared employing sol–gel and solid-reaction method. Its crystal-structure, microstructure, element-distribution, mechanical and thermophysical properties are investigated. The analytical conclusions reveal that this high-entropy oxide shows single pyrochlore structure, dense microstructure, and even element distribution. Owing to the strong phonon scattering originated from high-entropy effect and numerous oxygen vacancies, it has low thermal conductivity and ranges from 1.41 to 1.27 W/m. K. Its coefficient of thermal expansion is less than those of rare-earth cerium oxides and greater than that of 7YSZ. The Young's modulus of this high-entropy oxide is in the same order with 7YSZ, its Vickers hardness and fracture-toughness are lower than those of 7YSZ. This high-entropy oxide is also of excellent lattice-stability up to 1200 °C.
ISSN:2238-7854