Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand
Mn(II), Co(II), Ni(II), Cu(II), and Cr(III) metal complexes with the ligand (L) [3-(2nitro benzylidene) amino-2-thioxoimidazolidin-4-one] have been prepared and characterized in their solid state using the elemental micro analysis (C.H.N.S), flame atomic absorption, UV-Vis spectroscopy, FT-IR, magn...
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| Format: | Article |
| Language: | English |
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University of Baghdad
2017-02-01
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| Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| Subjects: | |
| Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/15 |
| _version_ | 1817982495330664448 |
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| author | Sinan Midhat Al-Bayati Anaam Majeed Rasheed Enas Zuhair Mohammed Zeina Kudair Hassan Amjad Chali Amal Mohammed Hussein |
| author_facet | Sinan Midhat Al-Bayati Anaam Majeed Rasheed Enas Zuhair Mohammed Zeina Kudair Hassan Amjad Chali Amal Mohammed Hussein |
| author_sort | Sinan Midhat Al-Bayati |
| collection | DOAJ |
| description |
Mn(II), Co(II), Ni(II), Cu(II), and Cr(III) metal complexes with the ligand (L) [3-(2nitro benzylidene) amino-2-thioxoimidazolidin-4-one] have been prepared and characterized in their solid state using the elemental micro analysis (C.H.N.S), flame atomic absorption, UV-Vis spectroscopy, FT-IR, magnetic susceptibility measurements, and electrical molar conductivity. The ratio of metal to ligand [M:L] was got for all complexes in the ethanol by using the molar ratio method, which produced comparable results with those results obtained for the solid complexes. From the data of all techniques, octahedral geometry was proposed for Cr(III), Mn(II), and Co(II) complexes, while tetrahedral structure was proposed for Ni(II), Cu(II) complexes.
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| first_indexed | 2024-04-13T23:21:27Z |
| format | Article |
| id | doaj.art-3f18ad9073d546208c131e23e305b3eb |
| institution | Directory Open Access Journal |
| issn | 1609-4042 2521-3407 |
| language | English |
| last_indexed | 2024-04-13T23:21:27Z |
| publishDate | 2017-02-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| spelling | doaj.art-3f18ad9073d546208c131e23e305b3eb2022-12-22T02:25:14ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072017-02-01293Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as LigandSinan Midhat Al-BayatiAnaam Majeed RasheedEnas Zuhair MohammedZeina Kudair HassanAmjad ChaliAmal Mohammed Hussein Mn(II), Co(II), Ni(II), Cu(II), and Cr(III) metal complexes with the ligand (L) [3-(2nitro benzylidene) amino-2-thioxoimidazolidin-4-one] have been prepared and characterized in their solid state using the elemental micro analysis (C.H.N.S), flame atomic absorption, UV-Vis spectroscopy, FT-IR, magnetic susceptibility measurements, and electrical molar conductivity. The ratio of metal to ligand [M:L] was got for all complexes in the ethanol by using the molar ratio method, which produced comparable results with those results obtained for the solid complexes. From the data of all techniques, octahedral geometry was proposed for Cr(III), Mn(II), and Co(II) complexes, while tetrahedral structure was proposed for Ni(II), Cu(II) complexes. https://jih.uobaghdad.edu.iq/index.php/j/article/view/15Synthesis, Characterization, Bidentate Schiff Base, Transition Metal Complexes. |
| spellingShingle | Sinan Midhat Al-Bayati Anaam Majeed Rasheed Enas Zuhair Mohammed Zeina Kudair Hassan Amjad Chali Amal Mohammed Hussein Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand Ibn Al-Haitham Journal for Pure and Applied Sciences Synthesis, Characterization, Bidentate Schiff Base, Transition Metal Complexes. |
| title | Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand |
| title_full | Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand |
| title_fullStr | Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand |
| title_full_unstemmed | Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand |
| title_short | Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand |
| title_sort | synthesis and characterization of transition metals ions complexes with 2 thioxoimidazolidin 4 one schiff base as ligand |
| topic | Synthesis, Characterization, Bidentate Schiff Base, Transition Metal Complexes. |
| url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/15 |
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