Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools

Powder mixtures based on copper or iron are used as metal binder materials in the manufacturing of abrasive and cutting tools. This article discusses some aspects and possibilities of using a high-energy ball milling process to modify the structure and properties of Cu-Sn, Cu-Sn-Ti and Fe-Ti powders...

Full description

Bibliographic Details
Main Authors: Pyotr Vityaz, Svetlana Kovaliova, Viktor Zhornik, Tatiana Grigoreva, Nikolay Lyakhov
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Powders
Subjects:
Online Access:https://www.mdpi.com/2674-0516/2/2/24
_version_ 1797592905190211584
author Pyotr Vityaz
Svetlana Kovaliova
Viktor Zhornik
Tatiana Grigoreva
Nikolay Lyakhov
author_facet Pyotr Vityaz
Svetlana Kovaliova
Viktor Zhornik
Tatiana Grigoreva
Nikolay Lyakhov
author_sort Pyotr Vityaz
collection DOAJ
description Powder mixtures based on copper or iron are used as metal binder materials in the manufacturing of abrasive and cutting tools. This article discusses some aspects and possibilities of using a high-energy ball milling process to modify the structure and properties of Cu-Sn, Cu-Sn-Ti and Fe-Ti powders, their sintered materials and composites with diamond. The structures of powders and sintered materials, as well as the binder-to-diamond interfaces in metal matrix composites with diamond fillers, were studied by XRD analysis, scanning electron microscopy and X-ray spectroscopy. Tribological properties and thermal stability of materials in the temperature range of 250–800 °C were investigated. Various mechanisms of dispersion strengthening during the heating of sintered materials are described. It is shown that due to the grain boundary distribution of titanium, it is possible to obtain single-phase powders in the form of a supersaturated solid solution of CuSn20Ti5 and FeTi20, which ensure the formation of thermally hardened alloys with a microhardness of 357–408 HV and 561–622 HV, respectively, in the temperature range of 350–800 °C. The wear resistance of sintered powder alloys increases more than twice. Furthermore, the simultaneous enhancement in both the strength and ductility of metal–diamond titanium-containing composites is achieved through the nanostructural state and the formation of a thin layer (up to 2 μm) of titanium carbide at the interface between the metal matrix and diamond. The developed alloy shows great potential as a binder in diamond tools which are designed for machining abrasive materials.
first_indexed 2024-03-11T01:59:44Z
format Article
id doaj.art-3f3670e10c604b99b959f7606b4333d3
institution Directory Open Access Journal
issn 2674-0516
language English
last_indexed 2024-03-11T01:59:44Z
publishDate 2023-05-01
publisher MDPI AG
record_format Article
series Powders
spelling doaj.art-3f3670e10c604b99b959f7606b4333d32023-11-18T12:14:45ZengMDPI AGPowders2674-05162023-05-012240342010.3390/powders2020024Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond ToolsPyotr Vityaz0Svetlana Kovaliova1Viktor Zhornik2Tatiana Grigoreva3Nikolay Lyakhov4The Joint Institute of Mechanical Engineering of the NAS of Belarus, 12 Akademicheskaya Str., 220072 Minsk, BelarusThe Joint Institute of Mechanical Engineering of the NAS of Belarus, 12 Akademicheskaya Str., 220072 Minsk, BelarusThe Joint Institute of Mechanical Engineering of the NAS of Belarus, 12 Akademicheskaya Str., 220072 Minsk, BelarusInstitute of Solid State Chemistry and Mechanochemistry of SB RAS, 18 Kutateladze Str., Novosibirsk 630090, RussiaInstitute of Solid State Chemistry and Mechanochemistry of SB RAS, 18 Kutateladze Str., Novosibirsk 630090, RussiaPowder mixtures based on copper or iron are used as metal binder materials in the manufacturing of abrasive and cutting tools. This article discusses some aspects and possibilities of using a high-energy ball milling process to modify the structure and properties of Cu-Sn, Cu-Sn-Ti and Fe-Ti powders, their sintered materials and composites with diamond. The structures of powders and sintered materials, as well as the binder-to-diamond interfaces in metal matrix composites with diamond fillers, were studied by XRD analysis, scanning electron microscopy and X-ray spectroscopy. Tribological properties and thermal stability of materials in the temperature range of 250–800 °C were investigated. Various mechanisms of dispersion strengthening during the heating of sintered materials are described. It is shown that due to the grain boundary distribution of titanium, it is possible to obtain single-phase powders in the form of a supersaturated solid solution of CuSn20Ti5 and FeTi20, which ensure the formation of thermally hardened alloys with a microhardness of 357–408 HV and 561–622 HV, respectively, in the temperature range of 350–800 °C. The wear resistance of sintered powder alloys increases more than twice. Furthermore, the simultaneous enhancement in both the strength and ductility of metal–diamond titanium-containing composites is achieved through the nanostructural state and the formation of a thin layer (up to 2 μm) of titanium carbide at the interface between the metal matrix and diamond. The developed alloy shows great potential as a binder in diamond tools which are designed for machining abrasive materials.https://www.mdpi.com/2674-0516/2/2/24metallic bindercopper–tin–titaniumiron–titaniumhigh-energy ball millingmechanical alloyingdiamond metal matrix composites
spellingShingle Pyotr Vityaz
Svetlana Kovaliova
Viktor Zhornik
Tatiana Grigoreva
Nikolay Lyakhov
Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
Powders
metallic binder
copper–tin–titanium
iron–titanium
high-energy ball milling
mechanical alloying
diamond metal matrix composites
title Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
title_full Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
title_fullStr Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
title_full_unstemmed Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
title_short Mechanical Alloying of Copper- or Iron-Based Metallic Binders for Diamond Tools
title_sort mechanical alloying of copper or iron based metallic binders for diamond tools
topic metallic binder
copper–tin–titanium
iron–titanium
high-energy ball milling
mechanical alloying
diamond metal matrix composites
url https://www.mdpi.com/2674-0516/2/2/24
work_keys_str_mv AT pyotrvityaz mechanicalalloyingofcopperorironbasedmetallicbindersfordiamondtools
AT svetlanakovaliova mechanicalalloyingofcopperorironbasedmetallicbindersfordiamondtools
AT viktorzhornik mechanicalalloyingofcopperorironbasedmetallicbindersfordiamondtools
AT tatianagrigoreva mechanicalalloyingofcopperorironbasedmetallicbindersfordiamondtools
AT nikolaylyakhov mechanicalalloyingofcopperorironbasedmetallicbindersfordiamondtools