Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols
Transetherifications between ethers and alcohols are fundamental organic reactions that are frequently used for the preparations of unsymmetrical ethers. In this article, the authors challenge the fundamental tenets of the traditional transetherification mechanism via systematic experimental and com...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2023-04-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-023-37538-1 |
| _version_ | 1827970356443348992 |
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| author | Hongmei Liu Qing Huang Rong-zhen Liao Man Li Youwei Xie |
| author_facet | Hongmei Liu Qing Huang Rong-zhen Liao Man Li Youwei Xie |
| author_sort | Hongmei Liu |
| collection | DOAJ |
| description | Transetherifications between ethers and alcohols are fundamental organic reactions that are frequently used for the preparations of unsymmetrical ethers. In this article, the authors challenge the fundamental tenets of the traditional transetherification mechanism via systematic experimental and computational investigations of a Re2O7-mediated annulation. |
| first_indexed | 2024-04-09T18:52:35Z |
| format | Article |
| id | doaj.art-3f574e523a7f406a9d4ed236d497340b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-09T18:52:35Z |
| publishDate | 2023-04-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-3f574e523a7f406a9d4ed236d497340b2023-04-09T11:20:44ZengNature PortfolioNature Communications2041-17232023-04-011411910.1038/s41467-023-37538-1Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcoholsHongmei Liu0Qing Huang1Rong-zhen Liao2Man Li3Youwei Xie4Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyHubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyHubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyHubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyHubei Key Laboratory of Bioinorganic Chemistry and Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and TechnologyTransetherifications between ethers and alcohols are fundamental organic reactions that are frequently used for the preparations of unsymmetrical ethers. In this article, the authors challenge the fundamental tenets of the traditional transetherification mechanism via systematic experimental and computational investigations of a Re2O7-mediated annulation.https://doi.org/10.1038/s41467-023-37538-1 |
| spellingShingle | Hongmei Liu Qing Huang Rong-zhen Liao Man Li Youwei Xie Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols Nature Communications |
| title | Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols |
| title_full | Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols |
| title_fullStr | Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols |
| title_full_unstemmed | Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols |
| title_short | Ring-closing C–O/C–O metathesis of ethers with primary aliphatic alcohols |
| title_sort | ring closing c o c o metathesis of ethers with primary aliphatic alcohols |
| url | https://doi.org/10.1038/s41467-023-37538-1 |
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