Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C

Thermodynamic description of the Fe-B-C system in its iron-rich corner is developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C) database. The thermodynamic parameters of the binary sub-systems, Fe-B, Fe-C and B-C, are taken from earlier assessments modifying the B-C description. Th...

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Main Authors: J. Miettinen, V.-V. Visuri, T. Fabritius, G. Vassilev
Format: Article
Language:English
Published: Polish Academy of Sciences 2020-05-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/116077/PDF/AMM-2020-2-54-Visuri.pdf
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author J. Miettinen
V.-V. Visuri
T. Fabritius
G. Vassilev
author_facet J. Miettinen
V.-V. Visuri
T. Fabritius
G. Vassilev
author_sort J. Miettinen
collection DOAJ
description Thermodynamic description of the Fe-B-C system in its iron-rich corner is developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C) database. The thermodynamic parameters of the binary sub-systems, Fe-B, Fe-C and B-C, are taken from earlier assessments modifying the B-C description. The parameters of the Fe-B-C system are optimized in this study using experimental thermodynamic and phase equilibrium data from the literature. Liquid, beta-rhombo-B and graphite phases are described using the substitutional solution model, while the ferrite (bcc), the austenite (fcc), the cementite (M3C) and the M23C6 phases are described with the sublattice model and the borides, Fe2B, FeB and B4C, are treated as stoichiometric phases. A good correlation was obtained between the calculated and the experimental thermodynamic and phase equilibrium data. The description is recommended to be used at the composition region of wt% C + wt% B < 15 and at temperatures below 2700oC.
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spelling doaj.art-3f9d7379dfd1488ebb2fc3a11f05e27c2022-12-22T03:41:51ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092020-05-01vol. 65No 2923933https://doi.org/10.24425/amm.2020.132840Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-CJ. MiettinenV.-V. VisuriT. FabritiusG. VassilevThermodynamic description of the Fe-B-C system in its iron-rich corner is developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C) database. The thermodynamic parameters of the binary sub-systems, Fe-B, Fe-C and B-C, are taken from earlier assessments modifying the B-C description. The parameters of the Fe-B-C system are optimized in this study using experimental thermodynamic and phase equilibrium data from the literature. Liquid, beta-rhombo-B and graphite phases are described using the substitutional solution model, while the ferrite (bcc), the austenite (fcc), the cementite (M3C) and the M23C6 phases are described with the sublattice model and the borides, Fe2B, FeB and B4C, are treated as stoichiometric phases. A good correlation was obtained between the calculated and the experimental thermodynamic and phase equilibrium data. The description is recommended to be used at the composition region of wt% C + wt% B < 15 and at temperatures below 2700oC.https://journals.pan.pl/Content/116077/PDF/AMM-2020-2-54-Visuri.pdfphase diagramsthermodynamic modellingthermodynamic databasefe-b-x systemsfe-b-c system
spellingShingle J. Miettinen
V.-V. Visuri
T. Fabritius
G. Vassilev
Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
Archives of Metallurgy and Materials
phase diagrams
thermodynamic modelling
thermodynamic database
fe-b-x systems
fe-b-c system
title Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
title_full Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
title_fullStr Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
title_full_unstemmed Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
title_short Thermodynamic Description of Ternary Fe-B-X Systems. Part 7: Fe-B-C
title_sort thermodynamic description of ternary fe b x systems part 7 fe b c
topic phase diagrams
thermodynamic modelling
thermodynamic database
fe-b-x systems
fe-b-c system
url https://journals.pan.pl/Content/116077/PDF/AMM-2020-2-54-Visuri.pdf
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AT vvvisuri thermodynamicdescriptionofternaryfebxsystemspart7febc
AT tfabritius thermodynamicdescriptionofternaryfebxsystemspart7febc
AT gvassilev thermodynamicdescriptionofternaryfebxsystemspart7febc