Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride
Green solvents for cellulose dissolution is a key topic for green chemistry, especially natural cellulose with high molecular weight, and there are scarce solvents reported. Deep eutectic solvent (DES) is a typical kind of green solvent that has been attracted much attention recently. Here, high mol...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2020-04-01
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| Series: | Green Energy & Environment |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025720300297 |
| _version_ | 1818332790145417216 |
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| author | Jiake Wang Yan Wang Zhongzheng Ma Lifeng Yan |
| author_facet | Jiake Wang Yan Wang Zhongzheng Ma Lifeng Yan |
| author_sort | Jiake Wang |
| collection | DOAJ |
| description | Green solvents for cellulose dissolution is a key topic for green chemistry, especially natural cellulose with high molecular weight, and there are scarce solvents reported. Deep eutectic solvent (DES) is a typical kind of green solvent that has been attracted much attention recently. Here, high molecular weight natural cellulose (DP > 3000) was first isolated from wheat straw and then be directly dissolved in the choline/l-lysine (Ch/Lys) DES. The solution owns excellent stability, and the solubility reaches ∼5%. Rheological studies revealed that the natural cellulose can be well dispersed in the DES solution and showed gelation at high concentrations. The dissolved cellulose can be regenerated when the dilute acid aqueous solution was added into the solution. It provides an energy conversation and an environmentally friendly route to prepare a cellulose solution, which makes it possible to convert cellulose to valuable chemicals and materials in its homogeneous solution. |
| first_indexed | 2024-12-13T13:41:20Z |
| format | Article |
| id | doaj.art-3faff8a757f7411cb145e36607e2fe70 |
| institution | Directory Open Access Journal |
| issn | 2468-0257 |
| language | English |
| last_indexed | 2024-12-13T13:41:20Z |
| publishDate | 2020-04-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Green Energy & Environment |
| spelling | doaj.art-3faff8a757f7411cb145e36607e2fe702022-12-21T23:43:35ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572020-04-0152232239Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochlorideJiake Wang0Yan Wang1Zhongzheng Ma2Lifeng Yan3CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, iCHEM, University of Science and Technology of China, Hefei, 230026, ChinaCAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, iCHEM, University of Science and Technology of China, Hefei, 230026, ChinaCAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, iCHEM, University of Science and Technology of China, Hefei, 230026, ChinaCorresponding author.; CAS Key Laboratory of Soft Matter Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemical Physics, iCHEM, University of Science and Technology of China, Hefei, 230026, ChinaGreen solvents for cellulose dissolution is a key topic for green chemistry, especially natural cellulose with high molecular weight, and there are scarce solvents reported. Deep eutectic solvent (DES) is a typical kind of green solvent that has been attracted much attention recently. Here, high molecular weight natural cellulose (DP > 3000) was first isolated from wheat straw and then be directly dissolved in the choline/l-lysine (Ch/Lys) DES. The solution owns excellent stability, and the solubility reaches ∼5%. Rheological studies revealed that the natural cellulose can be well dispersed in the DES solution and showed gelation at high concentrations. The dissolved cellulose can be regenerated when the dilute acid aqueous solution was added into the solution. It provides an energy conversation and an environmentally friendly route to prepare a cellulose solution, which makes it possible to convert cellulose to valuable chemicals and materials in its homogeneous solution.http://www.sciencedirect.com/science/article/pii/S2468025720300297Deep eutectic solvent (DES)Choline/l-Lysine hydrochlorideWheat strawNatural celluloseSolvent |
| spellingShingle | Jiake Wang Yan Wang Zhongzheng Ma Lifeng Yan Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride Green Energy & Environment Deep eutectic solvent (DES) Choline/l-Lysine hydrochloride Wheat straw Natural cellulose Solvent |
| title | Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride |
| title_full | Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride |
| title_fullStr | Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride |
| title_full_unstemmed | Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride |
| title_short | Dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of Choline/l-Lysine hydrochloride |
| title_sort | dissolution of highly molecular weight cellulose isolated from wheat straw in deep eutectic solvent of choline l lysine hydrochloride |
| topic | Deep eutectic solvent (DES) Choline/l-Lysine hydrochloride Wheat straw Natural cellulose Solvent |
| url | http://www.sciencedirect.com/science/article/pii/S2468025720300297 |
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