Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions

Synthesis of the [11]Cyclacene Framework by Repetitive Diels–Alder Cycloadditions

The Diels–Alder cycloaddition between bisdienes and bisdienophile incorporating the 7-oxa-bicyclo[2.2.1]heptane unit are well known to show high diastereoselectivity that can be exploited for the synthesis of molecular belts. The related bisdiene 5,6,7,8-tetramethylidene-2-bicyclo[2.2.2]octene is a...

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Bibliographic Details
Main Authors: John B. Bauer, Fatima Diab, Cäcilia Maichle-Mössmer, Hartmut Schubert, Holger F. Bettinger
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Molecules
Subjects:
Diels–Alder reaction
cyclacene
diastereoselectivity
zigzag hydrocarbon belt
density functional theory
cycloaddition
Online Access:https://www.mdpi.com/1420-3049/26/10/3047

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