Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution

Sodium oxalate has negative effects on alumina produced by the Bayer process. The behavior of sodium oxalate in the seeded precipitation process of a sodium aluminate solution was investigated. The particle size and morphology of crystallization, as well as the crystal habit of sodium oxalate, and t...

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Váldodahkkit: FAN Shang, CHEN Wen-mi, LIANG Gao-jie
Materiálatiipa: Artihkal
Giella:zho
Almmustuhtton: Science Press 2018-01-01
Ráidu:工程科学学报
Fáttát:
Liŋkkat:http://cje.ustb.edu.cn/article/doi/10.13374/j.issn2095-9389.2018.01.007
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author FAN Shang
CHEN Wen-mi
LIANG Gao-jie
author_facet FAN Shang
CHEN Wen-mi
LIANG Gao-jie
author_sort FAN Shang
collection DOAJ
description Sodium oxalate has negative effects on alumina produced by the Bayer process. The behavior of sodium oxalate in the seeded precipitation process of a sodium aluminate solution was investigated. The particle size and morphology of crystallization, as well as the crystal habit of sodium oxalate, and the interaction between sodium oxalate and gibbsite in synthetic or industrial sodium aluminate solutions were also investigated. The results show that sodium oxalate precipitates on the surface or gibbsite clearance, such that the secondary nucleation of gibbsite increases, and the agglomeration of gibbsite is seriously hindered. This is considered as the main cause of gibbsite refinement.
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spelling doaj.art-3fbff93aa84a428297cbc04cf061847e2024-10-18T06:34:26ZzhoScience Press工程科学学报2095-93892018-01-01401515810.13374/j.issn2095-9389.2018.01.007Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solutionFAN Shang0CHEN Wen-mi1LIANG Gao-jie2School of Metallurgy and Environment, Central South University, Changsha 410083, ChinaSchool of Metallurgy and Environment, Central South University, Changsha 410083, ChinaSchool of Metallurgy and Environment, Central South University, Changsha 410083, ChinaSodium oxalate has negative effects on alumina produced by the Bayer process. The behavior of sodium oxalate in the seeded precipitation process of a sodium aluminate solution was investigated. The particle size and morphology of crystallization, as well as the crystal habit of sodium oxalate, and the interaction between sodium oxalate and gibbsite in synthetic or industrial sodium aluminate solutions were also investigated. The results show that sodium oxalate precipitates on the surface or gibbsite clearance, such that the secondary nucleation of gibbsite increases, and the agglomeration of gibbsite is seriously hindered. This is considered as the main cause of gibbsite refinement.http://cje.ustb.edu.cn/article/doi/10.13374/j.issn2095-9389.2018.01.007sodium aluminate solutionseeded precipitationsodium oxalategranularity
spellingShingle FAN Shang
CHEN Wen-mi
LIANG Gao-jie
Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
工程科学学报
sodium aluminate solution
seeded precipitation
sodium oxalate
granularity
title Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
title_full Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
title_fullStr Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
title_full_unstemmed Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
title_short Behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
title_sort behavior of sodium oxalate in seeded precipitation process of sodium aluminate solution
topic sodium aluminate solution
seeded precipitation
sodium oxalate
granularity
url http://cje.ustb.edu.cn/article/doi/10.13374/j.issn2095-9389.2018.01.007
work_keys_str_mv AT fanshang behaviorofsodiumoxalateinseededprecipitationprocessofsodiumaluminatesolution
AT chenwenmi behaviorofsodiumoxalateinseededprecipitationprocessofsodiumaluminatesolution
AT lianggaojie behaviorofsodiumoxalateinseededprecipitationprocessofsodiumaluminatesolution