The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs

Abstract During application, energetic materials may suffer different temperature environmental stimulation. In order to study the influence of temperature environmental on performance of HNIW/FOX-7 based PBXs, HNIW/FOX-7 based PBX modeling powders and PBX columns were treated by LT (low temperature...

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Main Authors: Mengnan Zhou, Shusen Chen, Hui Chao, Na Wang, Bo Yan, Guanchao Lan, Shaohua Jin
Format: Article
Language:English
Published: Nature Portfolio 2022-03-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-08752-6
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author Mengnan Zhou
Shusen Chen
Hui Chao
Na Wang
Bo Yan
Guanchao Lan
Shaohua Jin
author_facet Mengnan Zhou
Shusen Chen
Hui Chao
Na Wang
Bo Yan
Guanchao Lan
Shaohua Jin
author_sort Mengnan Zhou
collection DOAJ
description Abstract During application, energetic materials may suffer different temperature environmental stimulation. In order to study the influence of temperature environmental on performance of HNIW/FOX-7 based PBXs, HNIW/FOX-7 based PBX modeling powders and PBX columns were treated by LT (low temperature), HT (high temperature), HLC (high-low temperature cycle) and HLS (high-low temperature shock). Then scanning electron microscope (SEM), infrared spectra (IR), X-ray diffraction (XRD) and differential scanning calorimetry (DSC) were used to study the variation of PBX modeling powders after LT, HT, HLC and HLS treatments; in addition, the mass, size and mechanical properties of PBX columns were characterized after different temperature adaptability treatments as well. The results indicate that the change ratios of mass and size of HNIW/FOX-7 based PBX columns are less than 1%, illustrating that mass and size of PBX columns are at acceptable level after different temperature adaptability treatments. The unevenness degree of the surface of PBX modeling powders followed the order of HLC > HT > LT > HLS, which agrees well with mass loss order. Moreover, IR and XRD results indicated that the molecular structure and crystal form of HNIW and FOX-7 did not change after different temperature adaptability treatments. Additionally, thermal stabilities of PBX modeling powders are decreased after different temperature adaptability treatments, among which HLS has the largest influence on HNIW/FOX-based PBX modeling powders. The compression strengths and elastic moduli of HNIW/FOX-based PBX columns are enhanced after different temperature adaptability treatments, among which the strength of PBX columns after HLC has the maximum increase, indicating that HLC has more significant effect on mechanical property.
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spelling doaj.art-3fd612c2473b44c5923db6266e4686a72022-12-22T02:39:33ZengNature PortfolioScientific Reports2045-23222022-03-0112111210.1038/s41598-022-08752-6The influence of temperature environmental on performance of HNIW/FOX-7 based PBXsMengnan Zhou0Shusen Chen1Hui Chao2Na Wang3Bo Yan4Guanchao Lan5Shaohua Jin6School of Materials Science and Engineering, Beijing Institute of TechnologySchool of Materials Science and Engineering, Beijing Institute of TechnologyResearch Institute, Gansu Yin Guang Chemical Industry Group Co. LtdResearch Institute, Gansu Yin Guang Chemical Industry Group Co. LtdResearch Institute, Gansu Yin Guang Chemical Industry Group Co. LtdResearch Institute, Gansu Yin Guang Chemical Industry Group Co. LtdSchool of Materials Science and Engineering, Beijing Institute of TechnologyAbstract During application, energetic materials may suffer different temperature environmental stimulation. In order to study the influence of temperature environmental on performance of HNIW/FOX-7 based PBXs, HNIW/FOX-7 based PBX modeling powders and PBX columns were treated by LT (low temperature), HT (high temperature), HLC (high-low temperature cycle) and HLS (high-low temperature shock). Then scanning electron microscope (SEM), infrared spectra (IR), X-ray diffraction (XRD) and differential scanning calorimetry (DSC) were used to study the variation of PBX modeling powders after LT, HT, HLC and HLS treatments; in addition, the mass, size and mechanical properties of PBX columns were characterized after different temperature adaptability treatments as well. The results indicate that the change ratios of mass and size of HNIW/FOX-7 based PBX columns are less than 1%, illustrating that mass and size of PBX columns are at acceptable level after different temperature adaptability treatments. The unevenness degree of the surface of PBX modeling powders followed the order of HLC > HT > LT > HLS, which agrees well with mass loss order. Moreover, IR and XRD results indicated that the molecular structure and crystal form of HNIW and FOX-7 did not change after different temperature adaptability treatments. Additionally, thermal stabilities of PBX modeling powders are decreased after different temperature adaptability treatments, among which HLS has the largest influence on HNIW/FOX-based PBX modeling powders. The compression strengths and elastic moduli of HNIW/FOX-based PBX columns are enhanced after different temperature adaptability treatments, among which the strength of PBX columns after HLC has the maximum increase, indicating that HLC has more significant effect on mechanical property.https://doi.org/10.1038/s41598-022-08752-6
spellingShingle Mengnan Zhou
Shusen Chen
Hui Chao
Na Wang
Bo Yan
Guanchao Lan
Shaohua Jin
The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
Scientific Reports
title The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
title_full The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
title_fullStr The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
title_full_unstemmed The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
title_short The influence of temperature environmental on performance of HNIW/FOX-7 based PBXs
title_sort influence of temperature environmental on performance of hniw fox 7 based pbxs
url https://doi.org/10.1038/s41598-022-08752-6
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