Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe

Thermoelectric energy conversion is one of the most important and desirable functions of materials, because the ability to recycle a part of the energy wasted as heat back to useful electric energy significantly contributes to a sustainable soc...

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Main Authors: S. Shimano, Y. Tokura, Y. Taguchi
Format: Article
Language:English
Published: AIP Publishing LLC 2017-05-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4983404
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author S. Shimano
Y. Tokura
Y. Taguchi
author_facet S. Shimano
Y. Tokura
Y. Taguchi
author_sort S. Shimano
collection DOAJ
description Thermoelectric energy conversion is one of the most important and desirable functions of materials, because the ability to recycle a part of the energy wasted as heat back to useful electric energy significantly contributes to a sustainable society in future. For practical applications of thermoelectric materials, sufficiently high conversion efficiency is required over a wide range of temperature. It is also desirable that the materials are composed of non-toxic elements from an environmental perspective. In this paper, we report the successful control of the hole-type charge carrier density in GeTe-based materials by co-doping Bi and Cu, and the resultant improvement in the thermoelectric figure of merit over a wide range of temperature from room temperature to around 800 K, especially below 500 K, compared to those of previously reported analogous materials, thereby demonstrating the potential of GeTe-based materials for practical applications.
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spelling doaj.art-3fd875f121d04d39a53cf559068c9d5b2022-12-21T19:02:15ZengAIP Publishing LLCAPL Materials2166-532X2017-05-0155056103056103-610.1063/1.4983404006705APMCarrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTeS. Shimano0Y. Tokura1Y. Taguchi2RIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198, JapanRIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198, JapanRIKEN Center for Emergent Matter Science (CEMS), Wako 351-0198, JapanThermoelectric energy conversion is one of the most important and desirable functions of materials, because the ability to recycle a part of the energy wasted as heat back to useful electric energy significantly contributes to a sustainable society in future. For practical applications of thermoelectric materials, sufficiently high conversion efficiency is required over a wide range of temperature. It is also desirable that the materials are composed of non-toxic elements from an environmental perspective. In this paper, we report the successful control of the hole-type charge carrier density in GeTe-based materials by co-doping Bi and Cu, and the resultant improvement in the thermoelectric figure of merit over a wide range of temperature from room temperature to around 800 K, especially below 500 K, compared to those of previously reported analogous materials, thereby demonstrating the potential of GeTe-based materials for practical applications.http://dx.doi.org/10.1063/1.4983404
spellingShingle S. Shimano
Y. Tokura
Y. Taguchi
Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
APL Materials
title Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
title_full Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
title_fullStr Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
title_full_unstemmed Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
title_short Carrier density control and enhanced thermoelectric performance of Bi and Cu co-doped GeTe
title_sort carrier density control and enhanced thermoelectric performance of bi and cu co doped gete
url http://dx.doi.org/10.1063/1.4983404
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AT ytokura carrierdensitycontrolandenhancedthermoelectricperformanceofbiandcucodopedgete
AT ytaguchi carrierdensitycontrolandenhancedthermoelectricperformanceofbiandcucodopedgete