Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene

Polypropylene (PP) has a high recycling potential. However, the properties of mechanically recycled PP (R-PP) have not been fully compared to those of virgin PP (V-PP). Therefore, in this study, properties of R-PP and V-PP were compared using data from recyclers, virgin plastic suppliers, and the li...

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Main Authors: Abdelhak Ladhari, Esra Kucukpinar, Henning Stoll, Sven Sängerlaub
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Recycling
Subjects:
Online Access:https://www.mdpi.com/2313-4321/6/4/76
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author Abdelhak Ladhari
Esra Kucukpinar
Henning Stoll
Sven Sängerlaub
author_facet Abdelhak Ladhari
Esra Kucukpinar
Henning Stoll
Sven Sängerlaub
author_sort Abdelhak Ladhari
collection DOAJ
description Polypropylene (PP) has a high recycling potential. However, the properties of mechanically recycled PP (R-PP) have not been fully compared to those of virgin PP (V-PP). Therefore, in this study, properties of R-PP and V-PP were compared using data from recyclers, virgin plastic suppliers, and the literature. The properties of recyclates could not be directly correlated either with the properties of the virgin polymers from which the recyclates were made or the recycling parameters. It was found that the MFR of R-PP was higher; MFR R-PP had a median value (m) of 11 g/10 min while MFR V-PP had a median value of 6.3 g/10 min (at 230 °C and with 2.16 kg). In terms of mechanical properties, in many cases R-PP exhibited stiffer and more brittle behavior, with a slightly higher Young’s modulus (E<sub>R-PP</sub> = 1400 and E<sub>V-PP</sub> = 1200 MPa), a reduced elongation at break (<i>ɛb</i><sub>R-PP</sub> = 4 l.-% and <i>ɛb</i><sub>V-PP</sub> = 83 l.-%), and notched charpy impact strength (NCIS<sub>R-PP</sub> = 4.8 and NCIS<sub>V-PP</sub> = 7.5 kJ/m<sup>2</sup>). However, the values for every property had a broad distribution. In addition to existing information from the literature, our research sheds fresh light on the variation of the characteristics of recycled polypropylenes presently on the market.
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spelling doaj.art-3fe669b99e95420b9f3b8541ca8fb29a2023-11-23T10:21:32ZengMDPI AGRecycling2313-43212021-11-01647610.3390/recycling6040076Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin PolypropyleneAbdelhak Ladhari0Esra Kucukpinar1Henning Stoll2Sven Sängerlaub3Department of Mechanical, Automotive and Aeronautical Engineering, Munich University of Applied Sciences HM, Lothstraße 38, 80335 Munich, GermanyFraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Strasse 35, 85354 Freising, GermanyDepartment of Mechanical, Automotive and Aeronautical Engineering, Munich University of Applied Sciences HM, Lothstraße 38, 80335 Munich, GermanyDepartment of Mechanical, Automotive and Aeronautical Engineering, Munich University of Applied Sciences HM, Lothstraße 38, 80335 Munich, GermanyPolypropylene (PP) has a high recycling potential. However, the properties of mechanically recycled PP (R-PP) have not been fully compared to those of virgin PP (V-PP). Therefore, in this study, properties of R-PP and V-PP were compared using data from recyclers, virgin plastic suppliers, and the literature. The properties of recyclates could not be directly correlated either with the properties of the virgin polymers from which the recyclates were made or the recycling parameters. It was found that the MFR of R-PP was higher; MFR R-PP had a median value (m) of 11 g/10 min while MFR V-PP had a median value of 6.3 g/10 min (at 230 °C and with 2.16 kg). In terms of mechanical properties, in many cases R-PP exhibited stiffer and more brittle behavior, with a slightly higher Young’s modulus (E<sub>R-PP</sub> = 1400 and E<sub>V-PP</sub> = 1200 MPa), a reduced elongation at break (<i>ɛb</i><sub>R-PP</sub> = 4 l.-% and <i>ɛb</i><sub>V-PP</sub> = 83 l.-%), and notched charpy impact strength (NCIS<sub>R-PP</sub> = 4.8 and NCIS<sub>V-PP</sub> = 7.5 kJ/m<sup>2</sup>). However, the values for every property had a broad distribution. In addition to existing information from the literature, our research sheds fresh light on the variation of the characteristics of recycled polypropylenes presently on the market.https://www.mdpi.com/2313-4321/6/4/76recyclingpolypropylenepolypropylene recyclatesmechanical propertiesrheological propertiesautomotive
spellingShingle Abdelhak Ladhari
Esra Kucukpinar
Henning Stoll
Sven Sängerlaub
Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
Recycling
recycling
polypropylene
polypropylene recyclates
mechanical properties
rheological properties
automotive
title Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
title_full Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
title_fullStr Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
title_full_unstemmed Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
title_short Comparison of Properties with Relevance for the Automotive Sector in Mechanically Recycled and Virgin Polypropylene
title_sort comparison of properties with relevance for the automotive sector in mechanically recycled and virgin polypropylene
topic recycling
polypropylene
polypropylene recyclates
mechanical properties
rheological properties
automotive
url https://www.mdpi.com/2313-4321/6/4/76
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AT esrakucukpinar comparisonofpropertieswithrelevancefortheautomotivesectorinmechanicallyrecycledandvirginpolypropylene
AT henningstoll comparisonofpropertieswithrelevancefortheautomotivesectorinmechanicallyrecycledandvirginpolypropylene
AT svensangerlaub comparisonofpropertieswithrelevancefortheautomotivesectorinmechanicallyrecycledandvirginpolypropylene