High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube

Polymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily beca...

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Main Authors: Yongcun Zhou, Xiao Zhuang, Feixiang Wu, Feng Liu
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/8/11/398
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author Yongcun Zhou
Xiao Zhuang
Feixiang Wu
Feng Liu
author_facet Yongcun Zhou
Xiao Zhuang
Feixiang Wu
Feng Liu
author_sort Yongcun Zhou
collection DOAJ
description Polymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily because of the high interfacial thermal resistance between inorganic fillers. Herein, we developed a novel method through silver functionalized graphene nanosheets (GNS) and multiwalled carbon nanotube (MWCNT) composites with excellent thermal properties to meet the requirements of thermal management. The effects of composites on interfacial structure and properties of the composites were identified, and the microstructures and properties of the composites were studied as a function of the volume fraction of fillers. An ultrahigh thermal conductivity of 12.3 W/mK for polymer matrix composites was obtained, which is an approximate enhancement of 69.1 times compared to the polyvinyl alcohol (PVA) matrix. Moreover, these composites showed more competitive thermal conductivities compared to untreated fillers/PVA composites applied to the desktop central processing unit, making these composites a high-performance alternative to be used for thermal management.
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spelling doaj.art-3fecd238fc5c4b7bb0e75d776261c4ff2022-12-22T02:54:17ZengMDPI AGCrystals2073-43522018-10-0181139810.3390/cryst8110398cryst8110398High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon NanotubeYongcun Zhou0Xiao Zhuang1Feixiang Wu2Feng Liu3School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaSchool of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaSchool of Metallurgy and Environment, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaPolymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily because of the high interfacial thermal resistance between inorganic fillers. Herein, we developed a novel method through silver functionalized graphene nanosheets (GNS) and multiwalled carbon nanotube (MWCNT) composites with excellent thermal properties to meet the requirements of thermal management. The effects of composites on interfacial structure and properties of the composites were identified, and the microstructures and properties of the composites were studied as a function of the volume fraction of fillers. An ultrahigh thermal conductivity of 12.3 W/mK for polymer matrix composites was obtained, which is an approximate enhancement of 69.1 times compared to the polyvinyl alcohol (PVA) matrix. Moreover, these composites showed more competitive thermal conductivities compared to untreated fillers/PVA composites applied to the desktop central processing unit, making these composites a high-performance alternative to be used for thermal management.https://www.mdpi.com/2073-4352/8/11/398chemical modificationelectronics coolingthermal management nanocompositesthermal conductivitysilver nanoparticles
spellingShingle Yongcun Zhou
Xiao Zhuang
Feixiang Wu
Feng Liu
High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
Crystals
chemical modification
electronics cooling
thermal management nanocomposites
thermal conductivity
silver nanoparticles
title High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
title_full High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
title_fullStr High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
title_full_unstemmed High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
title_short High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
title_sort high performance thermal management nanocomposites silver functionalized graphene nanosheets and multiwalled carbon nanotube
topic chemical modification
electronics cooling
thermal management nanocomposites
thermal conductivity
silver nanoparticles
url https://www.mdpi.com/2073-4352/8/11/398
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AT xiaozhuang highperformancethermalmanagementnanocompositessilverfunctionalizedgraphenenanosheetsandmultiwalledcarbonnanotube
AT feixiangwu highperformancethermalmanagementnanocompositessilverfunctionalizedgraphenenanosheetsandmultiwalledcarbonnanotube
AT fengliu highperformancethermalmanagementnanocompositessilverfunctionalizedgraphenenanosheetsandmultiwalledcarbonnanotube