High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube
Polymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily beca...
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MDPI AG
2018-10-01
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Online Access: | https://www.mdpi.com/2073-4352/8/11/398 |
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author | Yongcun Zhou Xiao Zhuang Feixiang Wu Feng Liu |
author_facet | Yongcun Zhou Xiao Zhuang Feixiang Wu Feng Liu |
author_sort | Yongcun Zhou |
collection | DOAJ |
description | Polymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily because of the high interfacial thermal resistance between inorganic fillers. Herein, we developed a novel method through silver functionalized graphene nanosheets (GNS) and multiwalled carbon nanotube (MWCNT) composites with excellent thermal properties to meet the requirements of thermal management. The effects of composites on interfacial structure and properties of the composites were identified, and the microstructures and properties of the composites were studied as a function of the volume fraction of fillers. An ultrahigh thermal conductivity of 12.3 W/mK for polymer matrix composites was obtained, which is an approximate enhancement of 69.1 times compared to the polyvinyl alcohol (PVA) matrix. Moreover, these composites showed more competitive thermal conductivities compared to untreated fillers/PVA composites applied to the desktop central processing unit, making these composites a high-performance alternative to be used for thermal management. |
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spelling | doaj.art-3fecd238fc5c4b7bb0e75d776261c4ff2022-12-22T02:54:17ZengMDPI AGCrystals2073-43522018-10-0181139810.3390/cryst8110398cryst8110398High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon NanotubeYongcun Zhou0Xiao Zhuang1Feixiang Wu2Feng Liu3School of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaSchool of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaSchool of Metallurgy and Environment, Central South University, Changsha 410083, ChinaSchool of Materials Science and Engineering, Northwestern Polytechnical University, Xi’an 710072, ChinaPolymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess unsatisfactory thermal conductivity, primarily because of the high interfacial thermal resistance between inorganic fillers. Herein, we developed a novel method through silver functionalized graphene nanosheets (GNS) and multiwalled carbon nanotube (MWCNT) composites with excellent thermal properties to meet the requirements of thermal management. The effects of composites on interfacial structure and properties of the composites were identified, and the microstructures and properties of the composites were studied as a function of the volume fraction of fillers. An ultrahigh thermal conductivity of 12.3 W/mK for polymer matrix composites was obtained, which is an approximate enhancement of 69.1 times compared to the polyvinyl alcohol (PVA) matrix. Moreover, these composites showed more competitive thermal conductivities compared to untreated fillers/PVA composites applied to the desktop central processing unit, making these composites a high-performance alternative to be used for thermal management.https://www.mdpi.com/2073-4352/8/11/398chemical modificationelectronics coolingthermal management nanocompositesthermal conductivitysilver nanoparticles |
spellingShingle | Yongcun Zhou Xiao Zhuang Feixiang Wu Feng Liu High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube Crystals chemical modification electronics cooling thermal management nanocomposites thermal conductivity silver nanoparticles |
title | High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube |
title_full | High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube |
title_fullStr | High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube |
title_full_unstemmed | High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube |
title_short | High-Performance Thermal Management Nanocomposites: Silver Functionalized Graphene Nanosheets and Multiwalled Carbon Nanotube |
title_sort | high performance thermal management nanocomposites silver functionalized graphene nanosheets and multiwalled carbon nanotube |
topic | chemical modification electronics cooling thermal management nanocomposites thermal conductivity silver nanoparticles |
url | https://www.mdpi.com/2073-4352/8/11/398 |
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